“…Reference value averaged per year [11] 20 30 n/a n/a n/a 5 n/a As a result of works connected with the exploration and recognition of deposits of natural gas from unconventional accumulations 2 sorts of waste are generated [1, 5, 6, The main sources of contaminants present in the drilling waste are chemicals used for compiling and regulation of parameters of technological drilling fluids, biocides, petroleum substances, corrosion inhibitors, chemicals used for completion of deposits and stimulation of inflow of hydrocarbons and reservoir fluids -which are most often brines and crude oil [1,6] Each drilling fluid has an increased pH value, increased amounts of undissolved and dissolved solid substances (Total dissolves solids -TDS) [1,14,15], surfactants, chloride and sulphate ions and dissolved organic carbon (Total organic carbon -TOC). It also includes small amounts of petroleum-derived hydrocarbons [1,15,16], heavy metals (such as: arsenic, cadmium, barium, chromium, copper, mercury, nickel, lead, antimony, selenium, zinc, tin, cobalt) [1,14,15,17] and also trace amounts of radioactive substances which come from shale formations [1,12,14].…”