Polyaniline-Pt and polypyrrole-Pt nanocomposites: Effect of supporting type and morphology on the nanoparticles size and distribution

Lemos, Hugo G.; Santos, Sydney Ferreira; Venâncio, Everaldo C.

doi:10.1016/j.synthmet.2015.02.006

Cited by 28 publications

(12 citation statements)

References 32 publications

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“…The nanocomposites formed are very sensitive to the matrix morphologies. Small polymer nanostructure (nanofibers) provides a large number of heterogeneous nucleation sites for nucleating Pt nanoparticles, leading to better distribution and dispersion of the Pt nanoparticles (2 nM) [129]. Mishra et al designed a new biosensor for the detection of human C-reactive protein (αCRP), by combining two types of advanced materials with complementary properties, polypyrrole film (PPy) and platinum nanoparticles (PtNPs).…”

Section: Platinum Nanoparticles-polymermentioning

confidence: 99%

Recent progress in nanocomposites based on conducting polymer: application as electrochemical sensors

et al. 2018

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Over the years, intensive research works have been devoted to conducting polymers due to their potential application in many fields such as fuel cell, sensors, and capacitors. To improve the properties of these compounds, several new approaches have been developed which consist in combining conducting polymers and nanoparticles. Then, this review intends to give a clear overview on nanocomposites based on conducting polymers, synthesis, characterization, and their application as electrochemical sensors. For this, the paper is divided into two parts: the first part will highlight the nanocomposites synthesized by combination of carbon nanomaterials (CNMs) and conducting polymers. The preparation of polymer/CNMs such as graphene and carbon nanotube modified electrode is presented coupled with relevant applications. The second part consists of a review of nanocomposites synthesized by combination of metal nanoparticles and conducting polymers.

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Section: Platinum Nanoparticles-polymermentioning

confidence: 99%

Recent progress in nanocomposites based on conducting polymer: application as electrochemical sensors

et al. 2018

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“…Immobilization of metal nanoparticles on conducting polymer host matrix prevents agglomeration of the nanoparticles, thereby improving the catalytic efficiency due to increase in electroactive surface area of the electrode . Some of the important conducting polymers (CPs) utilized as supporting host matrices for the dispersion of metal nanoparticles are polyaniline (PANI), polyacetylene (PAC), polythiophene (PT), polypyrrole (PPy) and poly(3,4‐ethylenedioxythiophene) (PEDOT) . Among the listed polymers, PANI is significantly important owing to its low cost, high conductivity, ease of synthesis, excellent electrical properties, good environmental stability and large variety of applications such as electrochromic devices, secondary batteries, catalysis, and corrosion protection coatings.…”

Section: Introductionmentioning

confidence: 99%

TEMPO‐Mediated Aqueous Phase Electrooxidation of Pyridyl Methanol at Palladium‐Decorated PANI on Carbon Fiber Paper Electrode

et al. 2020

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Palladium nanoparticles decorated on polyaniline coated carbon fiber paper electrode (Pd‐PANI/CFP) was employed for TEMPO ((2,2,6,6‐tetramethylpiperidin‐1‐yl)oxyl) mediated electrocatalytic oxidation of pyridyl methanol to pyridyl carboxaldehyde using cyclic voltammetry in aqueous acidic media using a surfactant. The electrochemical properties of the modified electrodes were studied by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The physicochemical properties of the modified electrodes were studied using Scanning electron microscopy (SEM) with Energy dispersive X‐ray spectroscopy (EDS), Transmission electron microscopy (TEM), Optical profilometry, X‐ray diffraction (XRD) spectroscopy, Raman spectroscopy and Fourier transform infrared (FTIR) spectroscopy. Pd‐PANI/CFP electrode has exhibited enhanced electrocatalytic activity towards TEMPO mediated oxidation of pyridyl methanol owing to higher electrochemically active surface area of the modified electrode. CV studies suggested higher electrochemical activity for Pd‐PANI/CFP electrode when compared to PANI/CFP and bare CFP electrodes towards TEMPO mediated oxidation of pyridyl methanol.

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“…Hybrid materials, based on conducting polymers (CP) and inorganic materials, attracted a lot of interest from past two decades [1,2] . Metal nanoparticles, carbon nanotubes and inorganic semiconducting materials as composites have been synthesized along with the conducting polymers in order to exploit their synergistic properties [3][4][5][6] . The high chance of construction for high quality of CP/SC interfaces, which can provide by hybrid assemblies of CPs and inorganic SCs while photo catalysis, solar cells, sensors and super capacitors in the account of enable as a wide range of promising applications [7,8] .…”

Section: Introductionmentioning

confidence: 99%

Hybrid Nanostructures

Venkatesh¹,

Saha²

2017

JPP

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Polyaniline-Pt and polypyrrole-Pt nanocomposites: Effect of supporting type and morphology on the nanoparticles size and distribution

Cited by 28 publications

References 32 publications

Recent progress in nanocomposites based on conducting polymer: application as electrochemical sensors

Recent progress in nanocomposites based on conducting polymer: application as electrochemical sensors

TEMPO‐Mediated Aqueous Phase Electrooxidation of Pyridyl Methanol at Palladium‐Decorated PANI on Carbon Fiber Paper Electrode

Hybrid Nanostructures

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