Polymere Phthalocyanine und ihre Vorstufen, 3. In situ Gasphasensynthese und einführende elektrochemische Charakterisierung polymerer Phthalocyanine auf metallischen Trägern

Bannehr, Rüdiger; Jaeger, N. I.; Meyer, Georg; Wöhrle, Dieter

doi:10.1002/macp.1981.021821011

Cited by 22 publications

(5 citation statements)

References 15 publications

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“…These results matched well with previous reports for the preparation of polymeric Pcs. 20,[27][28][29][30] FTIR spectra of polymer (4) (Figure 3 and Table 1) are typical for a polynuclear Pc and provide evidence for the structural skeleton of a Pc polymer such as the bands at 1069 and 1312 cm À1 , which can be traced to frame vibration of the pyrrole and benzene rings, respectively. 8,19 In addition, the broad band between 1700 cm À1 and 1600 cm À1 is characteristic for polynitrile structure of polymeric Pcs.…”

Section: Characterization Of In(iii)pc Polymer (4)mentioning

confidence: 99%

Indium(III) phthalocyanine eka-conjugated polymer as high-performance optical limiter upon nanosecond laser irradiation

Darwish

Al-Ashkar

2016

High Performance Polymers

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A novel chloroindium(III) phthalocyanine network polymer (4) was prepared and characterized by energy dispersive X-ray spectrometry, proton nuclear magnetic resonance, Fourier transform infrared spectroscopy, thermal gravimetric analysis (TGA) and absorption and emission spectroscopies. The non-linear optical (NLO) profile of the prepared phthalocyanine (Pc) network polymer, derived from a nanosecond open-aperture Z-scan technique at 532 nm, shows a clear reverse saturable absorption and a high non-linear absorption coefficient ( α2) of 9.7 × 10−7 cm W−1. Optical limiting investigations indicated that the prepared Pc network polymer has a relatively low limiting threshold of 900 mJ cm−2. According to these results, the prepared Pc polymer is a promising material for many NLO applications.

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Section: Characterization Of In(iii)pc Polymer (4)mentioning

confidence: 99%

Indium(III) phthalocyanine eka-conjugated polymer as high-performance optical limiter upon nanosecond laser irradiation

Darwish

Al-Ashkar

2016

High Performance Polymers

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“…Although these 2D solids have been known for many years [lo, 31,321, they are yet only poorly characterized. Improved methods for synthesis, however, have been reported recently [33].…”

Section: Introductionmentioning

confidence: 99%

The two‐dimensional band structure of (polyphthalocyaninato)Ni(II)

Ramı́rez

Böhm

1988

Int J of Quantum Chemistry

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The two-dimensional (2D) band structure of (polyphthalocyaninato)Ni(II), Ni(ppc), has been analyzed by a self-consistent field (SCF) Hartree-Fock (HF) crystal orbital (CO) formalism based on an TNDO (intermediate neglect of differential overlap) type Hamiltonian. The calculated HF band gap of Ni(ppc) amounts to 0.24 eV. The highest filled band is a ringlike ulu combination (D4h symmetry label) localized at the carbon sites of the organic fragment. Remarkable hybridization in the valence band leads to the considerable band width he, of 2.92 eV. This value is close to the he, numbers which are conventionally encountered in onedimensional metallomacrocycles. The effective width of the P states in Ni(ppc) is 13.8 eV. In graphite a net T interval of 13.0 eV is predicted by the present co formalism; Le., the energetic distribution of the P electrons is roughly comparable in both 2D solids. The Ni 3d states in Ni(ppc) are far below the Fermi level which is calculated at -4.9 eV; they are predicted between -12.2 and -16.4 eV in the mean-field approximation. Quasi-particle corrections lead to a significant shift of these strongly metal-centered states. Important electronic structure properties of Ni(ppc) are compared with those of ID metallomacrocycles with similar molecular stoichiometry. The total density of states distribution of Ni(ppc) has been fragmented into projected (ligand T and u, Ni 3 4 contributions in order to allow for a transparent interpretation of the 2D band structure.

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“…By reaction of gaseous tetracarbonitriles like 1,2,4,5-tetracyanobenzene with metal surfaces thin films of the polymers were obtained. 8,9 More recently, the electropolymerisation of suitable substituted porphyrins 10 and phthalocyanines 11 was used for the formation of thin films of polymers of these macrocyclic compounds. In this case the monomers for electropolymerisation are substituted i.e.…”

Section: Introductionmentioning

confidence: 99%