2012
DOI: 10.1016/j.cattod.2011.12.003
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Polymerization of olefins with single-site catalyst anchored on amine-functionalized surface of SBA-15

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Cited by 30 publications
(17 citation statements)
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“…3c and d made it clear to observe channel-like structures running parallel to the longer direction. As reported in other literatures [29], these channels displayed in Fig. 3c corresponded well to the typical structure of SBA-15.…”
Section: Sem Tem and Nitrogen Adsorption-desorption Characterizationsupporting
confidence: 70%
“…3c and d made it clear to observe channel-like structures running parallel to the longer direction. As reported in other literatures [29], these channels displayed in Fig. 3c corresponded well to the typical structure of SBA-15.…”
Section: Sem Tem and Nitrogen Adsorption-desorption Characterizationsupporting
confidence: 70%
“…4) are identical, type IV with a clear type H 1 hysteresis loop which is typical for mesoporous materials that exhibit capillary condensation and evaporation and possess large www.elsevier.com/locate/nbt 7 pore sizes [31]. BET and BJH analysis demonstrated a decrease in BET surface area and pore volume (Table 4) in the aminated MSS and the biocatalyst compared to the MSS proving a successful grafting [32]. The average pore diameters of MSS-NH 2 and E-MSS-NH 2 were similar and lower than that of the MSS, indicating that functionalized silanes were anchored on the pore surface ( Table 4).…”
Section: Physicochemical Characterization Of Carrier and Immobilized mentioning
confidence: 99%
“…The ethylene homo-and copolymerization activities of (n-BuCp) 2 ZrCl 2 supported on the amine-functionalized SBA-15 were increased with an increase in the nitrogen and Zr content in the supported catalyst. 15 In this study functionalizations of SBA-15 and SiO 2 with N -[(3-trimethoxysilyl)propyl]ethylenediamine (2NS) were carried out via a post-synthesis grafting method to anchor late transition metal precursors on the surface of SBA-15 and SiO 2 , and the performance of the prepared catalysts in L-lactide polymerization were examined briefly. The amine-functionalized SBA-15 and SiO 2 were used as supports for immobilization of Ni and Pd complex precursors.…”
Section: Introductionmentioning
confidence: 99%