The
Sinian Doushantuo Formation has been identified as a promising
shale gas reservoir in South China and potentially worldwide. This
study aims to restore the paleo-temperature and paleo-pressure characteristics
of the Doushantuo Formation, found in the Yichang area, western Hubei,
and to study the significance of overpressure on shale gas preservation
and enrichment using petrographic, cathodoluminescence (CL), microthermometry,
and Raman spectroscopy techniques on the composite veins. Single-phase
methane inclusions and two-phase aqueous inclusions were consistently
observed in the same fluid inclusion assemblage (FIA), indicating
that the fluid inclusions trapped during fracture cementation were
saturated with methane-rich hydrocarbon fluid. The CL image analysis
demonstrated that the formation of veins in the shale occurred in
two different stages, consistent with the results of the homogenization
temperature (Th) analysis. The trapping pressures of the methane inclusions
ranged from 81.95 to 95.00 MPa and from 57.13 to 63.62 Ma in the calcite
and quartz veins, respectively, as predicted by the combination of
the methane inclusion density and Th of the coexisting aqueous inclusions
and the equations of state for the supercritical methane. The calculated
pressure coefficient (Pc) of 1.90–2.31 indicates that fluid
inclusions were trapped in the medium-to-high overpressure state.
The Ths of the fluid inclusions are lower than that of the maximum
paleo-temperature (∼230 °C), indicating that these fluid
inclusions were trapped after the maximum burial and first rapid uplifting
process (∼165 Ma). These trapped diachronous fluid inclusions
can provide crucial evidence for the formation and evolution of the
identified overpressure. Our results suggest that the paleo-overpressure
in the Doushantuo shale was continually released through high-angle
fractures during the multistage uplifts, deposition, and reuplifting
in the Yanshanian and Himalayan movements, resulting in normal pressure
and low gas content.