Pore-Size Engineering of Silicon Imido Nitride for Catalytic Applications

Farrusseng, David; Schlichte, Klaus; Spliethoff, Bernd; Wingen, Annette; Kaskel, Stefan; Bradley, John S.; Schüth, Ferdi

doi:10.1002/1521-3773(20011119)40:22<4204::aid-anie4204>3.0.co;2-d

Cited by 69 publications

(42 citation statements)

References 38 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Microporous silicon nitride has been prepared using sol-gel templating on long chain amines and showed a higher selectivity over nontemplated silicon nitride in the catalysis of alkylation and isomerization reactions. 26 A number of porous silicon nitride structures have also been prepared using sol-gel chemistry without a template, including highsurface-area aerogels, 27 membranes, 28,29 and mesoporous powders. 30 Sol-gel processes have also been used to obtain titanium nitride materials.…”

Section: Introductionmentioning

confidence: 99%

Template Infiltration Routes to Ordered Macroporous TiN and SiN_x Films

et al. 2009

View full text Add to dashboard Cite

Ordered macroporous films of nanocrystalline TiN and amorphous SiN x on silica substrates have been prepared. This involved infiltration of sacrificial templates of close-packed polystyrene microsphere arrays with precursor materials, followed by pyrolysis under ammonia to remove the template and form the ceramic materials. TiN was prepared from a sol-gel route, whereas SiN x was introduced using a Si(NHMe) 4 precursor solution. Hexane was found to be the solvent most compatible with the divinylbenzene-cross-linked polystyrene template and was used for both materials.

show abstract

Section: Introductionmentioning

confidence: 99%

Template Infiltration Routes to Ordered Macroporous TiN and SiN_x Films

et al. 2009

View full text Add to dashboard Cite

show abstract

“…Catalytic applications of mesoporous materials are not limited to oxides. Micro-and meso-porous silicon imido nitride obtained by an organic selfassembly method showed pore-size dependent selectivity for isomerization of alkenes or alkylation of alkylbenzenes [91].…”

Section: Self-assembly Of Precursor Moleculesmentioning

confidence: 99%

Self-assembled materials for catalysis

Zhu

Wang

2009

Nano Res.

View full text Add to dashboard Cite

The purpose of this review is to highlight developments in self-assembled nanostructured materials (i.e., mesoporous and nanoparticle-based materials) and their catalytic applications. Since there are many available reviews of metal-based nanoparticles as catalysts, this review will mainly focus on self-assembled oxide-based catalytic materials. The content includes: (1) design and synthetic strategies for self-assembled mesoporous catalysts, (2) polyoxometalate (POM)-based nanocatalysts, (3) dendrimer-based nanocatalysts, and (4) shaped nanomaterials and catalytic applications. We show that controlled assembly of molecules, crystalline seeds, and nano building blocks into organized mesoscopic structures or controlled morphologies is an effective approach for tailoring porosities of heterogeneous catalysts and controlling their catalytic activities.

show abstract

“…One of the main advantages of the MOFs is their high surface area and exceptional porosity, which in particular exhibit great potential in the use of catalysts [5][6][7]. However, the low mechanical strength and block nature of the MOF products greatly prevent their application in these certain areas.…”

Section: Introductionmentioning

confidence: 99%

A facile strategy to fabricate carboxyl-rich carbon spheres with copper-based MOFs through coordination bond

Wang

et al. 2016

J Porous Mater

View full text Add to dashboard Cite

A new composite (CCSs/MOFs) of carboxylrich carbon spheres (CCSs) and copper-based metal-organic frameworks (MOFs) was for the first time prepared. The CCSs/MOFs composite was synthesized by the coordinated growth of high surface area and porous MOFs, [Cu 3 (BTC) 2 (H 2 O)] n (HKUST-1), on the surface of the functionalized CCSs obtained through a one-step hydrothermal carbonization of glucose with acrylic acid at 180°C for 24 h. The resulting composites showed a core/ shell structure with a tunable diameter arranging from 0.6 to 3.0 lm, and possessed high specific surface area of 495 m 2 /g and nanoporous structures derived from MOFs. Further, the catalytic oxidation of benzylic alcohol to benzaldehyde as its application was studied.

show abstract

Pore-Size Engineering of Silicon Imido Nitride for Catalytic Applications

Cited by 69 publications

References 38 publications

Template Infiltration Routes to Ordered Macroporous TiN and SiN_x Films

Template Infiltration Routes to Ordered Macroporous TiN and SiN_x Films

Self-assembled materials for catalysis

A facile strategy to fabricate carboxyl-rich carbon spheres with copper-based MOFs through coordination bond

Contact Info

Product

Resources

About

Pore-Size Engineering of Silicon Imido Nitride for Catalytic Applications

Cited by 69 publications

References 38 publications

Template Infiltration Routes to Ordered Macroporous TiN and SiNx Films

Template Infiltration Routes to Ordered Macroporous TiN and SiNx Films

Self-assembled materials for catalysis

A facile strategy to fabricate carboxyl-rich carbon spheres with copper-based MOFs through coordination bond

Contact Info

Product

Resources

About

Template Infiltration Routes to Ordered Macroporous TiN and SiN_x Films

Template Infiltration Routes to Ordered Macroporous TiN and SiN_x Films