Characteristics of predictable quantum efficient detector (PQED) by in terms of optical nonlinearity in the visible to near-infrared range were investigated under zero-bias and reverse-bias voltage conditions. In the zero-bias condition, linear behavior was observed in the wavelength from 405 nm to 1060 nm in the photocurrent range of 1 nA to 10 µA, and saturation occurred for photocurrents over 10 µA for all wavelengths. In the reverse-bias voltage of 10 V, the linear behavior was observed in the photocurrent range of 64 nA to 1 mA except for the wavelength of 1060 nm, and the saturation photocurrent increased up to 1 mA. Supralinearity value at 1060 nm sharply increased from the photocurrent of 100 µA, and its maximum value reached up to 0.34 % at the photocurrent of 1 mA because of the back surface recombination and the longer absorption length. The spectral linearity results of the PQED help us to understand the charge-carrier loss mechanism in the PQED, and would lead to more accurate optical measurement with it.