1989
DOI: 10.1021/ic00305a028
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Preparation and characterization of a binuclear iron-.mu.-dioxygen complex: [(Ph3PO)4FeOOFe(OPPh3)4.cntdot.2H2O](ClO4)4

Abstract: Appendix m!(nl)! Consider a fixed molecular core geometry with m equivalent sites, each of which can be occupied by any one of n different metals. The number of possible metal stoichiometries is given by eq A I . The total number of discrete molecules, N , dependson the core geometry. Examples: (1) N = 24 when n = 4 for the trinuclear core structures VA and VB (Table V); (2) N = 36 when n = 4 for the tetrahedral core structure I11 (Table VI). The combination of [Fe"(OPPh3)4](C104)2 with HOOH, m-C1C6H4C(0)OOH, … Show more

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Cited by 20 publications
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