Two series of poly(acrylamide-co-acrylates) with compositions ranging from 10 to 55 mol % acrylate units were prepared by radical polymerization in inverse microemulsions. The compositional analyses of the samples were performed using elemental analysis, potentiometry and 13C NMR. The comparison between the three methods indicates that "C NMR is the most reliable one, avoiding errors which often arise from assodated water in hydrophilic polymers. The copolymer viscosity exhibits a maximum behavior around 40 mol % acrylate content, a lower value than that already observed for copolymers prepared in homogeneous solution. The production of copolymers presenting high intrinsic viscosities (-3700 cm3g -1) is achieved using an inverse microemulsion as the polymerization medium operating at lower temperature.