“…The actual use of the azo dye is the most common and the most frequently applied, approximately 50%. The precursors and intermediates of azo dyes are carcinogenic, mutagenic and toxicity [3,4,5].Congo red is a typical benzidine azo dye in dyeing and printing industry, mainly for cotton, viscose dyeing and paper industry production [2,3,4,5].Currently Congo red dye wastewater treatment methods are commonly used in adsorption, membrane separation, chemical coagulation, oxidation, biological method [6,7,8].Adsorption method is an effective means of dyeing wastewater treatment, because of its convenient operation, simple process, low cost and good treatment effect have attracted much attention [9,10,11,12].…”