Type I crops (wheat and soybean), in which the potassium concentration (Kc) decreases when the nitrogen concentration (Nc) decreases, and type II crop (sunflower), in which Kc remains constant when Nc decreases, were grown in K-sufficient and K-deficient soils in pots. The CO 2 exchange rate (Pnet; photosynthetic rate, PR; photorespiratory rate, and DR; dark respiratory rate), the distribution of photosynthesized 14 C to organs, and the chemical compounds and free amino acids in fully expanded leaves were investigated. The results obtained can be summarized as follows.