Line structures are an essential part in integrated circuit (IC) fabrication. In photolithography, the electromagnetic scattering of line structures is one of the main factors that determine the advancement of the technology node. From the perspective of modeling, a theoretical model to physically understand the scattering phenomenon is necessary for a solid foundation in efficient Abstract _____________________________________________________________________________________________ _____________________________________________________________________________________________ iii ERT model, the electromagnetic field that causes a disturbance in the amplitude profile for the total solution was identified and explained in detail. The accuracy of the ERT model was also verified by comparing with the finite difference time domain (FDTD) solution. For a single polysilicon line structure with width of 1.66 λ (λ is the wavelength) on silicon substrate, the developed ERT model was able to demonstrate amplitude correlation coefficient (ACC) of 0.978 and the maximum amplitude difference, Δ|Ez| of as low as-0.067. The subwavelength line width of 0.4 λ was identified as the limit of the ERT model for the single polysilicon line structure. The study of alignment marks focuses on their performance to meet the stringent overlay requirement for advanced technology node process. The simulation results obtained from rigorous coupled wave analysis (RCWA) demonstrated that by incorporating small periodic structure into the conventional alignment mark, the reflected diffraction efficiency was improved at the respective order. The experimental works were performed for 90 nm and 0.11 µm processes. It is demonstrated that overlay as low as 9 nm was achieved when 5th order mark was used for the 90 nm technology node front-end-of-line (FEOL) process. Narrow marks for backend-end-of-line (BEOL) process also showed compatible results with the lowest overlay of 10 nm. _____________________________________________________________________________________________ v of this work. In addition, the experiments would not be possible without the technical support from ASM Lithography, Mr. Lim Ser Yong and Mr. Alex Chew. To all my peers in Chartered Special Project (SP) group, in particular Clark, Timonthy, Caroline, Jia Mei, Suey Li, Gek Soon and Alan, I thoroughly enjoyed the time that we had spent in the SP room. I think the feeling is mutual. Thank you for making my student days in Chartered a memorable one. I would also like to thank Jone for her generous help to proofread all the chapters in this thesis. Last but not least, I would like to thank my parents for their everlasting and unconditional support throughout my graduate studies. Their caring has motivated me to enjoy every second in my daily life, even during the most difficult times of my research work. Table of Contents _____________________________________________________________________________________________