Coalbed methane (CBM)
is an important unconventional energy resource,
and its micropore structure has a vital impact on its exploitation.
Based on the nuclear magnetic resonance (NMR) experiment, the low-temperature
liquid nitrogen adsorption experiment, and the contact angle experiment,
in this paper, we investigated the influence of nanofluids on the
micropore structure of a CBM reservoir from many aspects. The influence
of different adsorption mechanisms of TiO2 nanoparticles
on the surface wettability of rock samples was analyzed. The influence
of nanoparticle adsorption on the drainage and distribution of liquid
in the rock sample was discussed in depth. In addition, the effects
of nanofluid treatment on the micropore structure were investigated
by comparing the data of low-temperature liquid nitrogen adsorption
experiments, including the pore diameter, pore volume, and specific
surface area (SSA). The experimental results show that the treatment
of nanofluids helps to open the micropores and greatly increases the
SSA, pore diameter, and pore volume of the sample. The maximum increase
percentages of SSA, pore volume, and pore diameter are 228.12, 80.65,
and 18.89%, respectively. It is found that the adsorption of particles
is conducive to enhancing the water wettability of the pore throat
surface and reducing the damage to water locks.