2004
DOI: 10.1590/s0103-50532004000500005
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Properties of [Pd2X2(dppm)2] (X = Cl, SnCl3, dppm = Bis(diphenylphosphino)methane) complexes on porous vycor glass

Abstract: Neste trabalho o vidro poroso Vycor foi utilizado como matriz para a imobilização de complexos contendo ligação metal-metal [Pd 2 Cl 2 (dppm) 2 ], [Pd 2 (SnCl 3 )Cl(dppm) 2 ] e [Pd 2 (SnCl 3 ) 2 (dppm) 2 ] A elevada reatividade das ligações metal-metal em reações de inserção de moléculas como CO e SO 2 é preservada no meio poroso, sendo reversível sob vácuo. Os espectros de RMN MAS 31 P, refletância difusa no infravermelho e Raman indicaram que há uma gama de interações possíveis entre o vidro e as moléculas, … Show more

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Cited by 3 publications
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“…These porous surface contains silanol groups, with acid hydrogens (pK a $ 9), which can be used as active sites for the incorporation of several compounds. A great variety of nanocomposites with PVG has been successfully produced using organometallic compounds, coordination compounds, semiconductors, oxides, and polymers to different goals [17,[23][24][25][26][27][28].…”
Section: Introductionmentioning
confidence: 99%
“…These porous surface contains silanol groups, with acid hydrogens (pK a $ 9), which can be used as active sites for the incorporation of several compounds. A great variety of nanocomposites with PVG has been successfully produced using organometallic compounds, coordination compounds, semiconductors, oxides, and polymers to different goals [17,[23][24][25][26][27][28].…”
Section: Introductionmentioning
confidence: 99%