We investigate the electronic state and structure transition of BaNi2As2, which shows a similar superconducting phase diagram as Fe-based superconductors. We construct the ten-orbital tight-binding model for BaNi2As2 by using the maximally localized Wannier function method. The Coulomb and quadrupole-quadrupole interactions are treated within the random-phase approximation. We obtain the strong developments of charge quadrupole susceptibilities driven by the in-plane and out-of-plane oscillations of Ni ions. The largest susceptibility is either O X 2 −Y 2 -quadrupole susceptibility at q = (π, 0, π) or O XZ(Y Z) -quadrupole susceptibility at q = (π, π, π), depending on the level splitting between d X 2 −Y 2 and d XZ(YZ) . These antiferro-quadrupole fluctuations would then be the origin of the strong coupling superconductivity in Ni-based superconductors. Also, we propose that the antiferro-quadrupole O X 2 −Y 2 order with q = (π, 0, π) is the origin of the zigzag chain structure reported in experiments. We identify similarities and differences between Ni-and Fe-based superconductors.