Pyrotechnic compositions
are usually employed in time delay detonators
to facilitate controlled initiation of explosive charges in mining
and quarrying operations. Traditional slow-burning formulations are
problematic, as they contain heavy metals which are bio-accumulative
and toxic to the environment. A combination of traditional thermite
and intermetallic reactions using “green” reagents was
therefore investigated as a possible alternative. It was hypothesized
that the high thermite reaction temperature would ensure a sustained
intermetallic reaction, resulting in the desired slow-burning effect.
A ternary composition comprising manganese and tin as fuels mixed
with bismuth oxide as an oxidizer was used to explore this concept.
Burn rates ranging from 2.9 to 10.9 mm·s–1 were
obtained and were dependent on the relative proportions of the reagents.
Burn rate predictions, using a Padè mixture model, were in
close agreement with the measured data. The reaction products consisted
of mixtures of metal oxides, manganese stannate, and Mn3Sn, which was the only intermetallic formed. The slowest burning
compositions were those associated with the formation of this intermetallic
compound.