CNTs-TiO 2¯l ms with di®erent morphology were fabricated on stainless steel substrates through chemical vapor hydrolysis deposition (CVHD) process and sol-gel process, respectively. Their morphology was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The photocatalytic properties of the¯lms were tested in the degradation of methyl orange by UV light irradiation. The results revealed that TiO 2 nanoparticles could form a continuous layer on the surface of CNTs through CVHD process. While for sol-gel process, most TiO 2 nanoparticles were isolated and only a small amount of TiO 2 nanoparticles attached on the surface of CNTs. And the photocatalytic property of TiO 2 /CNTs¯lm synthesized through CVHD process was better than that of TiO 2 /CNTs¯lms synthesized through sol-gel process. Electrochemical impedance spectroscopy (EIS) analysis illuminated that TiO 2 /CNTs synthesized through CVHD process displayed a smaller resistance than the sample which was synthesized through sol-gel process and certi¯ed that the close combination between TiO 2 and CNTs could minimize recombination of photogenerated electrons and holes, and thus promote the photocatalytic property.