Realization of Ti MOF/MoS2 hybrid nanostructure and their catalytic activity towards 4-nitrophenol reduction

Coupled Co-Doped MoS2 and CoS2 as the Dual-Active Site Catalyst for Chemoselective Hydrogenation

“…12,13 When these unsaturated coordination sites are further promoted by Co or Ni atoms, MoS 2 -based catalysts can activate reactants more efficiently. 14−16 For the hydrogenation of substituted nitrobenzene, it has been reported that MoS 2based catalysts could efficiently catalyze the reduction of nitro compounds by using ammonia borane, 17 hydrazine monohydrate, 18 and NaBH 4 19,20 as the reducing agents. For example, Guardia et al 21 reported that single-layered chemically exfoliated MoS 2 nanosheets exhibited superior catalytic performance for the selective hydrogenation of nitro compounds using NaBH 4 as the hydrogen source.…”

“…Molybdenum disulfide (MoS 2 ) has been widely used as a high-efficiency catalyst for hydrodesulfurization and hydrodeoxygenation of petroleum, biomass, and coal-derived liquids. ,, The catalytic sites of MoS 2 are generally considered to be unsaturated coordination sites at the edges. , When these unsaturated coordination sites are further promoted by Co or Ni atoms, MoS 2 -based catalysts can activate reactants more efficiently. − For the hydrogenation of substituted nitrobenzene, it has been reported that MoS 2 -based catalysts could efficiently catalyze the reduction of nitro compounds by using ammonia borane, hydrazine monohydrate, and NaBH 4 , as the reducing agents. For example, Guardia et al reported that single-layered chemically exfoliated MoS 2 nanosheets exhibited superior catalytic performance for the selective hydrogenation of nitro compounds using NaBH 4 as the hydrogen source.…”

Stable 1T‐MoS2 by Facile Phase Transition Synthesis for Efficient Electrocatalytic Oxygen Evolution Reaction

“…[18][19][20] While many studies have explored MoS 2 -based materials for HER, the focus on applying such materials to OER has been limited. [21][22][23][24] In these regards, designing phase transformed 1T-MoS 2 based heterostructures can be a reasonable strategy to obtain effective electrocatalysts. For this, MOF is a good candidate material for the synthesis of 1T-MoS 2 based heterostructures, as the structure, surface area, and pore size of MOF are easily controllable to facilitate the phase transition of MoS 2 .…”

“…[25] However, most of these hybrid structures have shown low OER performances and lacked in comprehensive understanding for catalyst development toward the OER. [22][23][24] In this work, we seek to address these issues by proposing a combined theoretical and experimental exploration of facile synthesis of MoS 2 /MOF heterostructures. By incorporating NH 2 -MIL-125(Ti) (Ti MOF), phase-transformed MoS 2 was synthesized under mild conditions with the transition percentage of max.…”

MOF-templated synthesis of photoluminescent MoS2 QDs

“…Although there are many strategies available for synthesizing MoS 2 /MOF-related composites, [26][27][28] the fabrication of MoS 2 QDs in a porous MOF is still unfortunately a considerable challenge, and the direct synthesis of MoS 2 QDs in the pore of an MOF has not yet been reported. Several of reasons we address here.…”