Bias-stress
instability has been a challenging problem and a roadblock
for developing stable p-type organic field-effect transistors (OFETs).
This device instability is hypothesized because of electron-correlated
charge carrier trapping, neutralization, and recombination at semiconductor/dielectric
interfaces and in semiconductor channels. Here, in this paper, a strategy
is demonstrated to improve the bias-stress stability by constructing
a multilayered drain electrode with energy-level modification layers
(ELMLs). Several organic small molecules with high lowest unoccupied
molecular orbital (LUMO) energy levels are experimented as ELMLs.
The energy-level offset between the Fermi level of the drain electrode
and the LUMOs of the ELMLs is shown to construct the interfacial barrier,
which suppresses electron injection from the drain electrode into
the channel, leading to significantly improved bias-stress stability
of OFETs. The mechanism of the ELMLs on the bias-stress stability
is studied by quantitative modeling analysis of charge carrier dynamics.
Of all injection models evaluated, it is found that Fowler–Nordheim
tunneling describes best the observed experimental data. Both theory
and experimental data show that, by using the ELMLs with higher LUMO
levels, the electron injection can be suppressed effectively, and
the bias-stress stability of p-type OFETs can thereby be improved
significantly.