Removal strategies for endocrine disrupting chemicals using cellulose-based materials as adsorbents: A review

Tapia-Orozco, Natalia; IbarraCabrera, Ricardo; Tecante, Alberto; Gimeno, Miquel; Parra‐Saldívar, Roberto; García-Arrazola, Roeb

doi:10.1016/j.jece.2016.06.025

Cited by 65 publications

(23 citation statements)

References 161 publications

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“…Some of the endocrine disruptive effects of copper ions are: Increased levels of plasma cortisol associated with protein synthesis, cell proliferation, and apoptose in gill cells. It can also lead to an increase in Catecholamines which promotes metabolic and haematopoietic responses 1 , 2 . Several anthropogenic activities and natural phenomena release copper ions into the environment 3 .…”

Section: Introductionmentioning

confidence: 99%

Two–three parameters isotherm modeling, kinetics with statistical validity, desorption and thermodynamic studies of adsorption of Cu(II) ions onto zerovalent iron nanoparticles

Dada

Adekola

Odebunmi

et al. 2021

Sci Rep

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Adsorption of problematic copper ions as one of the endocrine disruptive substances from aqueous solution onto nanoscale zerovalent iron (nZVI) was studied. The high pore size 186.9268 Å, pore diameter 240.753 Å, and BET surface area 20.8643 m2 g−1 and pH(pzc) enlisted nZVI as an efficient nano-adsorbent for treatment of heavy metals from synthetic wastewater. SEM and EDX revealed the morphology and elemental distribution before and after adsorption. 98.31% removal efficiency was achieved at optimum adsorption operational parameters. Of all the thirteen isotherm models, equilibrium data were well fitted to Langmuir. Kinetics and mechanism data across the concentrations from 10 to 200 mg L−1 were analyzed by ten models. PSO best described kinetics data as confirmed by various statistical error validity models. The intraparticle diffusion model described that the intraparticle diffusion was not the only rate-limiting step. The adsorption mechanism was diffusion governed established by Bangham and Boyd models. Feasible, spontaneous, endothermic, and degree of randomness were reveal by the thermodynamic studies. Better desorption index and efficiency were obtained using HCl suggesting multiple mechanism processes. The performance of ZVI suggested it has a great potential for effective removal of endocrine disruptive cationic contaminant from wastewater.

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Section: Introductionmentioning

confidence: 99%

Two–three parameters isotherm modeling, kinetics with statistical validity, desorption and thermodynamic studies of adsorption of Cu(II) ions onto zerovalent iron nanoparticles

Dada

Adekola

Odebunmi

et al. 2021

Sci Rep

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“…The fabricated CNF-based 1D, 2D, and 3D materials have shown promising applications for the adsorption and removal of various pollutants from water [ 14 , 15 ]. Previously, a lot of reviews on the synthesis, functionalization, and applications of cellulose and CNFs have been released [ 16 , 17 , 18 , 19 , 20 ]. For example, Jonoobi et al summarized the preparation methods and properties of cellulose nanocrystals and CNFs, which were focused on the methodologies on the synthesis of nanostructured cellulose from natural resources [ 16 ].…”

Section: Introductionmentioning

confidence: 99%

Recent Advances in the Fabrication and Environmental Science Applications of Cellulose Nanofibril-Based Functional Materials

Zhang¹,

Guo

Wei

2021

Materials

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Cellulose is one of the important biomass materials in nature and has shown wide applications in various fields from materials science, biomedicine, tissue engineering, wearable devices, energy, and environmental science, as well as many others. Due to their one-dimensional nanostructure, high specific surface area, excellent biodegradability, low cost, and high sustainability, cellulose nanofibrils/nanofibers (CNFs) have been widely used for environmental science applications in the last years. In this review, we summarize the advance in the design, synthesis, and water purification applications of CNF-based functional nanomaterials. To achieve this aim, we firstly introduce the synthesis and functionalization of CNFs, which are further extended for the formation of CNF hybrid materials by combining with other functional nanoscale building blocks, such as polymers, biomolecules, nanoparticles, carbon nanotubes, and two-dimensional (2D) materials. Then, the fabrication methods of CNF-based 2D membranes/films, three-dimensional (3D) hydrogels, and 3D aerogels are presented. Regarding the environmental science applications, CNF-based nanomaterials for the removal of metal ions, anions, organic dyes, oils, and bio-contents are demonstrated and discussed in detail. Finally, the challenges and outlooks in this promising research field are discussed. It is expected that this topical review will guide and inspire the design and fabrication of CNF-based novel nanomaterials with high sustainability for practical applications.

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“…4,12,13 This limitation prompted researchers to scout for alternative adsorbents from a wide variety of materials, like waste and agricultural by-products, which are considered lowcost, efficient, available, and highly abundant. 3,[14][15][16] In this context, a wide variety of adsorbents have been developed to remove BPA from the aqueous phase, such as pomelo peel, corncobs, Eucalyptus globulus and silkworm excrement, 16 miscanthus straw, wheat straw, sowood, seed rape straw, sewage sludge, and rice husk, 17 barley husk, 18 argan nutshells, 19 and potato peel. 20 Many of them have limitations that make it necessary to explore other materials and to develop techniques that increase their adsorption capacity.…”

Section: Introductionmentioning

confidence: 99%

Production of modified sunflowers seed shells for the removal of bisphenol A

et al. 2021

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Removal strategies for endocrine disrupting chemicals using cellulose-based materials as adsorbents: A review

Cited by 65 publications

References 161 publications

Two–three parameters isotherm modeling, kinetics with statistical validity, desorption and thermodynamic studies of adsorption of Cu(II) ions onto zerovalent iron nanoparticles

Two–three parameters isotherm modeling, kinetics with statistical validity, desorption and thermodynamic studies of adsorption of Cu(II) ions onto zerovalent iron nanoparticles

Recent Advances in the Fabrication and Environmental Science Applications of Cellulose Nanofibril-Based Functional Materials

Production of modified sunflowers seed shells for the removal of bisphenol A

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