Research Into Structure of Argentium Nanoparticles Obtained From Varied Polymer Medium

Humbatova, S.F.; Mammadova, S.M.; Tapdigov, Sh.Z.; Safarov, N. A.; Abbasov, M.H.; Zeynalov, N.A.

doi:10.32737/2221-8688-2018-1-78-85

Cited by 2 publications

(2 citation statements)

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“…It is well-known, that polymers containing functional groups as the bearers are widely used for immobilization the number of complex-making sorbents, catalysts and biologically active substances [1][2][3]. The catalytic properties of such metal-polymer complexes were studied in the oxidation reactions of some paraffins and cycloparaffins and it was revealed, that they are higheffective catalyst [4,5].…”

Section: Introductionmentioning

confidence: 99%

RESEARCH INTO KINETIC REGULARITIES OF CATALYTIC LIQUID-PHASE OXIDATION OF n-HEXADECANE IN THE PRESENCE OF METALCOMPLEXES CALALYSTS

Suleymanova¹,

Zeynalov²,

Badalova³

et al. 2019

Chemical Problems

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Kinetic regularities of catalytic liquid-phase oxidation of n-hexadecane in the presence of metal complexes of variable valence were studied. In the reaction of n-hexadecane oxidation as a catalytic mixture, a complex o-phenanthroline with stearate with variable valence metals (Mn2+, Cu2+, Co2+) was used. It found that o-phenanthroline significantly influences the catalytic activity of metal ions. The introduction of organic ligand into the catalytic system, as well as varying the ligand: metal salt ratio, has effect greatly on the course and character of the process.

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Section: Introductionmentioning

confidence: 99%

RESEARCH INTO KINETIC REGULARITIES OF CATALYTIC LIQUID-PHASE OXIDATION OF n-HEXADECANE IN THE PRESENCE OF METALCOMPLEXES CALALYSTS

Suleymanova¹,

Zeynalov²,

Badalova³

et al. 2019

Chemical Problems

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“…As is known, functionalized polymers [13] and polymer composites with silver nanoparticles are widely used in medicine as carrier to immobilize bio-nanocomposites, bionanocatalysts, antibacterial drugs and biologically active substances depending on their particle size [14,15].…”

Section: Introductionmentioning

confidence: 99%

Research Into Sorbtion Properties and Structures of Polymer Hydrogel Immobilized by Doxorubicin

Mammadova¹,

Tapdigov²,

Humbatova³

et al. 2018

Chemical Problems

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The sorption of doxorubicin by hydrogeles obtained through cross-limking of polyacrylic acid with varied quantity (%, mass) of N, N-methylene-bis-acrylamide within pH = 1÷10 interval for 24 hours was performed. It revealed that protonation of active functional groups of hydrogel in acidic media (pH ≤ 4) impedes electrostatic interaction with identical charges in hydrogel and doxorubicin. A small degree of swelling at low pH of medium also impedes the penetration of molecule of antibiotic into internal pores of hydrogele. Note that pH changes toward alkaline medium, deprotonation and thereby negative charging of hydrogele surface leads to the sorption of positively charged molecule of doxorubicin. As the pH changes to the alkaline, the deprotonation of the hydrogel surface and, on the contrary, the negative loading that causes the easy sorption of positively charged doxorubicin molecule..On the other hand, the high swelling of hydrogel in alkaline medium also contributes to the increase of sorption level. Also, the nature of chemical interaction between hydrogel and antibiotic was examined by infrared spectroscopy methods, as well as by scanning electron microscopy. It found that the relation between the polymer and the doxorubicin occurs mainly due to hydrogen bond, electrostatic and hydrophobic interaction.

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Research Into Structure of Argentium Nanoparticles Obtained From Varied Polymer Medium

Cited by 2 publications

References 1 publication

RESEARCH INTO KINETIC REGULARITIES OF CATALYTIC LIQUID-PHASE OXIDATION OF n-HEXADECANE IN THE PRESENCE OF METALCOMPLEXES CALALYSTS

RESEARCH INTO KINETIC REGULARITIES OF CATALYTIC LIQUID-PHASE OXIDATION OF n-HEXADECANE IN THE PRESENCE OF METALCOMPLEXES CALALYSTS

Research Into Sorbtion Properties and Structures of Polymer Hydrogel Immobilized by Doxorubicin

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