The crystal structures of four complexes formed by 7,7,8, C ~2H4N4) and 1,2-di(2-thienyl)ethylene (DTE, C10HaS2), stilbene (STB, Ct4H12), 2,2',5,5 '-tetramethoxystilbene (TMS, C18H2004) and dithieno- The interplanar spacings correspond to the van der Waals separation. Disorder was found with respect to the DTE and STB molecules in these TCNQ complexes. Both molecules were treated by group refinement. Anisotropic electrical conductivities measured for all compounds are very low, corresponding to mixed-stack packing.