Few-layer
black phosphorus (BP) has attracted significant interest
in recent years due to electrical and photonic properties that are
far superior to those of other two-dimensional layered semiconductors.
The study of long term electrical stability and reliability of black
phosphorus field effect transistors (BP-FETs) with technologically
relevant thin, and device-selective, gate dielectrics, stressed under
realistic (closer to operation) bias and measured using state-of-the-art
ultrafast reliability characterization techniques, is essential for
their qualification and use in different applications. In this work,
air-stable BP-FETs with a thin top-gated dielectric (15 nm Al2O3, SiO2 equivalent thickness of 5 nm)
were fabricated and comprehensively characterized for threshold voltage
(V
th) instability under negative gate
bias stress at various measurement delays (t
m), stress biases (V
GSTR), temperatures
(T), and stress times (t
str) for the first time. Thin top-gated oxide enables low V
GSTR that is closer to the operating condition and ultrafast V
th measurements with low delay (t
m = 10 μs, due to high drain current) that ensure
minimal recovery. The resultant time kinetics of V
th degradation (ΔV
th) shows fast saturation at longer stress times and low-temperature
activation energy. V
th instability in
these top-gated devices is suggested to be dominated by hole trapping,
which is modeled using first-order equations at different V
GSTR and T. It is shown that measurements using
larger t
m show lower degradation magnitude
that do not saturate due to recovery artifacts and give inaccurate
estimation of hole trap densities. Conventional, thick, and global
back-gated oxide BP-FETs were also fabricated and characterized for
varying t
m (1 ms being the lowest due
to a low drain current level for thick oxide), V
GSTR, and T to benchmark our top-gated results.
Nonsaturating ΔV
th in the back-gated
devices is shown to result from recovery artifacts due to the large t
m (1 ms and greater) values. Finally, using
a V
GSTR and T-dependent first-order model,
we show that the top-gated Al2O3 BP-FETs with
scaled gate oxide thickness can match state-of-the-art Si reliability
specifications at operating voltage and room/elevated temperature.