Reversible environmental impacts of iron-based metal-organic framework MIL-53(Fe) on nitrogen-fixing bacterium Azotobacter vinelandii

Ouyang, Bowei; Chen, Qian; Yuan, Huahui; Hu, Ruonan; Liang, Chengzhuang; Liu, Fangshi; Pan, Lejie; Wu, Xian; Yang, Shengrong

doi:10.1016/j.jece.2022.107794

Cited by 10 publications

(2 citation statements)

References 49 publications

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“…Herein, the Raman spectra of FN-MIL and FN-MIL@NC-LDH were utilized to corroborate the decoration of NC-LDH on FN-MIL (Figure 2b). The peaks in FN-MIL@ NC-LDH located at 629 and 858 cm −1 are attributed to Fe−O and M−OH−M, 29,30 proving the synthesis of bimetallic MIL-53. Compared to FN-MIL, two new peaks in FN-MIL@NC-LDH at around 450 and 522 cm −1 are, respectively, Ni−O and Co−O, 31 signifying the existence of NC-LDH.…”

Section: Resultsmentioning

confidence: 92%

NiCo Nanolayered Double Hydroxides on Fe/Ni Metal–Organic Frameworks for Oxygen Evolution

Wang

Yang

2023

ACS Appl. Nano Mater.

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Modulation of oxygen intermediates in the oxygen evolution reaction (OER) tends to be an effective method for intensifying OER activity. In this paper, NiCo nanolayered double hydroxide (NC-LDH)-decorated FeNi bimetallic metal–organic framework (FN-MIL) heterostructures were constructed for enhanced OER performance. Various characteristics including Raman and Fourier-transform infrared spectra, X-ray diffraction patterns, scanning and transmission electron microscopy images, and X-ray photoelectron spectroscopy spectra help to explore the composition and microstructure. The band gap of samples was discussed using Mott–Schottky curves and Tauc plots to analyze the interfacial electron transfer driven by the energy level difference, resulting in the formation of electron-rich and electron-deficient regions at the interface and realizing the directed modulation of oxygen intermediates. The as-prepared composite catalyst revealed excellent OER performance, long-term stability, a high faradic efficiency of 97.8%, and a low potential of 244 mV at 10 mA cm–2 (without iR-compensation). Interestingly, the catalyst maintained high OER activity in seawater containing 1 M KOH due to its favorable resistance to chloride ions, suggesting an appealing prospect in practical application.

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Section: Resultsmentioning

confidence: 92%

NiCo Nanolayered Double Hydroxides on Fe/Ni Metal–Organic Frameworks for Oxygen Evolution

Wang

Yang

2023

ACS Appl. Nano Mater.

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“…[37] Notably, the Fe-O stretching band (632 cm −1 ) was detected. [38] These feature peaks were all de-tected in MoS 2 /MIL-53(Fe), indicating the successful synthesis of MoS 2 /MIL-53(Fe).…”

Section: Synthesis and Structure Characterizationsmentioning

confidence: 89%

Internal Electric Field‐Modulated Charge Migration Behavior in MoS₂/MIL‐53(Fe) S‐Scheme Heterojunction for Boosting Visible‐Light‐Driven Photocatalytic Chlorinated Antibiotics Degradation

Liu

Ning

Ren

et al. 2023

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Inadequate photo‐generated charge separation, migration, and utilization efficiency limit the photocatalytic efficiency. Herein, a MoS2/MIL‐53(Fe) photocatalyst/activator with the S‐scheme heterojunction structure is designed and the charge migration behavior is modulated by the internal electric field (IEF). The IEF intensity is enhanced to 40 mV by modulating band bending potential and the depletion layer length of MoS2. The photo‐generated electron migration process is boosted by constructing the electron migration bridge (Fe‐O‐S) and modulating the IEF as the driving force, confirmed by the density functional theory calculation. Compared with the pristine materials, the photocurrent density of MoS2/MIL‐53(Fe) is significantly enhanced 27.5 times. Contributed by the visible‐light‐driven cooperative catalytic degradation and the high‐efficiency direct photo‐generated electron reduction dichlorination process, satisfactory chlorinated antibiotics removal and detoxification performances are achieved. This study opens up new insights into the application of heterojunctions in photocatalytic activation of PDS in environmental remediation.

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Effects of iron-based metal–organic framework-MIL-53(Fe) and phosphorus-based flame retardants on the flame retardancy of high-density polyethylene

Liu,

Deng,

Zhao

et al. 2024

J Therm Anal Calorim

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Reversible environmental impacts of iron-based metal-organic framework MIL-53(Fe) on nitrogen-fixing bacterium Azotobacter vinelandii

Cited by 10 publications

References 49 publications

NiCo Nanolayered Double Hydroxides on Fe/Ni Metal–Organic Frameworks for Oxygen Evolution

NiCo Nanolayered Double Hydroxides on Fe/Ni Metal–Organic Frameworks for Oxygen Evolution

Internal Electric Field‐Modulated Charge Migration Behavior in MoS₂/MIL‐53(Fe) S‐Scheme Heterojunction for Boosting Visible‐Light‐Driven Photocatalytic Chlorinated Antibiotics Degradation

Effects of iron-based metal–organic framework-MIL-53(Fe) and phosphorus-based flame retardants on the flame retardancy of high-density polyethylene

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Reversible environmental impacts of iron-based metal-organic framework MIL-53(Fe) on nitrogen-fixing bacterium Azotobacter vinelandii

Cited by 10 publications

References 49 publications

NiCo Nanolayered Double Hydroxides on Fe/Ni Metal–Organic Frameworks for Oxygen Evolution

NiCo Nanolayered Double Hydroxides on Fe/Ni Metal–Organic Frameworks for Oxygen Evolution

Internal Electric Field‐Modulated Charge Migration Behavior in MoS2/MIL‐53(Fe) S‐Scheme Heterojunction for Boosting Visible‐Light‐Driven Photocatalytic Chlorinated Antibiotics Degradation

Effects of iron-based metal–organic framework-MIL-53(Fe) and phosphorus-based flame retardants on the flame retardancy of high-density polyethylene

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Product

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Internal Electric Field‐Modulated Charge Migration Behavior in MoS₂/MIL‐53(Fe) S‐Scheme Heterojunction for Boosting Visible‐Light‐Driven Photocatalytic Chlorinated Antibiotics Degradation