Inadequate photo‐generated charge separation, migration, and utilization efficiency limit the photocatalytic efficiency. Herein, a MoS2/MIL‐53(Fe) photocatalyst/activator with the S‐scheme heterojunction structure is designed and the charge migration behavior is modulated by the internal electric field (IEF). The IEF intensity is enhanced to 40 mV by modulating band bending potential and the depletion layer length of MoS2. The photo‐generated electron migration process is boosted by constructing the electron migration bridge (Fe‐O‐S) and modulating the IEF as the driving force, confirmed by the density functional theory calculation. Compared with the pristine materials, the photocurrent density of MoS2/MIL‐53(Fe) is significantly enhanced 27.5 times. Contributed by the visible‐light‐driven cooperative catalytic degradation and the high‐efficiency direct photo‐generated electron reduction dichlorination process, satisfactory chlorinated antibiotics removal and detoxification performances are achieved. This study opens up new insights into the application of heterojunctions in photocatalytic activation of PDS in environmental remediation.
The generation of large amounts of personal data provides data centers with sufficient resources to mine idiosyncrasy from private records. User modeling has long been a fundamental task with the goal of capturing the latent characteristics of users from their behaviors. However, centralized user modeling on collected data has raised concerns about the risk of data misuse and privacy leakage. As a result, federated user modeling has come into favor, since it expects to provide secure multi-client collaboration for user modeling through federated learning. Unfortunately, to the best of our knowledge, existing federated learning methods that ignore the inconsistency among clients cannot be applied directly to practical user modeling scenarios, and moreover, they meet the following critical challenges: 1) Statistical heterogeneity . The distributions of user data in different clients are not always independently identically distributed (IID), which leads to unique clients with needful personalized information; 2) Privacy heterogeneity . User data contains both public and private information, which have different levels of privacy, indicating that we should balance different information shared and protected; 3) Model heterogeneity . The local user models trained with client records are heterogeneous, and thus require a flexible aggregation in the server; 4) Quality heterogeneity . Low-quality information from inconsistent clients poisons the reliability of user models and offsets the benefit from high-quality ones, meaning that we should augment the high-quality information during the process. To address the challenges, in this paper, we first propose a novel client-server architecture framework, namely Hierarchical Personalized Federated Learning (HPFL), with a primary goal of serving federated learning for user modeling in inconsistent clients. More specifically, the client train and deliver the local user model via the hierarchical components containing hierarchical information from privacy heterogeneity to join collaboration in federated learning. Moreover, the client updates the personalized user model with a fine-grained personalized update strategy for statistical heterogeneity. Correspondingly, the server flexibly aggregates hierarchical components from heterogeneous user models in the case of privacy and model heterogeneity with a differentiated component aggregation strategy. In order to augment high-quality information and generate high-quality user models, we expand HPFL to the Augmented-HPFL (AHPFL) framework by incorporating the augmented mechanisms, which filters out low-quality information such as noise, sparse information and redundant information. Specially, we construct two implementations of AHPFL, i.e., AHPFL-SVD and AHPFL-AE, where the augmented mechanisms follow SVD (singular value decomposition) and AE (autoencoder), respectively. Finally, we conduct extensive experiments on real-world datasets, which demonstrate the effectiveness of both HPFL and AHPFL frameworks.
In the Natural Language for Optimization (NL4Opt) NeurIPS 2022 competition 1 , competitors focus on improving the accessibility and usability of optimization solvers, with the aim of subtask 1: recognizing the semantic entities that correspond to the components of the optimization problem; subtask 2: generating formulations for the optimization problem. In this paper, we present the solution of our team. First, we treat subtask 1 as a named entity recognition (NER) problem with the solution pipeline including pre-processing methods, adversarial training, postprocessing methods and ensemble learning. Besides, we treat subtask 2 as a generation problem with the solution pipeline including specially designed prompts, adversarial training, post-processing methods and ensemble learning. Our proposed methods have achieved the F1-score of 0.931 in subtask 1 and the accuracy of 0.867 in subtask 2, which won the fourth and third places respectively in this competition. Our code is available at https://github.com/bigdata-ustc/nl4opt.
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