1999
DOI: 10.1016/s0022-328x(98)01090-0
|View full text |Cite
|
Sign up to set email alerts
|

Ring-opening reactions of thiomorpholine and thiazolidine by [Ru3(CO)12]: crystal structures of [Ru3(μ-H)(μ-η2-SCH2CH2NH2)(CO)9] and [Ru2(μ-η3-SCH2CH2NHCH2)(CO)6]

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3

Citation Types

0
3
0

Year Published

2001
2001
2009
2009

Publication Types

Select...
4
1

Relationship

3
2

Authors

Journals

citations
Cited by 12 publications
(3 citation statements)
references
References 19 publications
0
3
0
Order By: Relevance
“…Many of the resultant complexes are biologically important as they can be used as models for metal-centers in metalloproteins 30,31,32,33,34 and also possess different industrial applications such as anticorrosion and as accelerators in the rubber vulcanization process. 35 The reactions of trimetallic clusters with nitrogen and sulfur containing heterocycles such as 4-methylthiazole, 12 2,4,5-trimethylthiazole, 9 thiazole, 13,16 thiomorpholine, 14 thiazolidine, 14 2methyl-2-thiazoline, 10 benzothiazole, 15 pyrimidine-2-thiol 15 and pyridine-2-thiol 11 have been demonstrated by us. The neutral ligand 2-mercapto-1-methylimidazole can in principle coordinates both in the 'thione' and in the tautomeric 'thiol' form (−NH−C=S⇌−N=C−SH−NH−C=S⇌−N=C−SH) which gives rise to a wide range of coordination compounds with considerable structural diversity.…”
Section: Introductionmentioning
confidence: 90%
See 1 more Smart Citation
“…Many of the resultant complexes are biologically important as they can be used as models for metal-centers in metalloproteins 30,31,32,33,34 and also possess different industrial applications such as anticorrosion and as accelerators in the rubber vulcanization process. 35 The reactions of trimetallic clusters with nitrogen and sulfur containing heterocycles such as 4-methylthiazole, 12 2,4,5-trimethylthiazole, 9 thiazole, 13,16 thiomorpholine, 14 thiazolidine, 14 2methyl-2-thiazoline, 10 benzothiazole, 15 pyrimidine-2-thiol 15 and pyridine-2-thiol 11 have been demonstrated by us. The neutral ligand 2-mercapto-1-methylimidazole can in principle coordinates both in the 'thione' and in the tautomeric 'thiol' form (−NH−C=S⇌−N=C−SH−NH−C=S⇌−N=C−SH) which gives rise to a wide range of coordination compounds with considerable structural diversity.…”
Section: Introductionmentioning
confidence: 90%
“…In recent years, the reactions of transition metal carbonyl clusters with heterocyclic ligands containing more than one hetero-atoms have been widely investigated. 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18 These reactions are markedly influenced by the structure of the heterocyclic ring, starting clusters and also by the reaction conditions employed. Trinuclear osmium clusters have proved to be useful system for modeling heterogeneous catalytic processes such as hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) which are associated with the cleavage of C-X bonds (X = S, N).…”
Section: Introductionmentioning
confidence: 99%
“…The study of the reactivity of nitrogen and sulfur containing small heterocyclic organic molecules towards transition metal carbonyl clusters has attracted considerable interest because such ligands frequently stabilizes the metal cluster framework by serving as chelating or bridging ligands 1,2,3,4,5 and also due to their potential applicability in modeling hydrodenitrogenation (HDN) and hydrodesulfurization (HDS) processes. 1,2,3,4,5,6,7 These reactions are usually accompanied by C-H, N-H, S-H and C-N bonds activation of the heterocyclic ligand and markedly influenced by the structure of the heterocycle as well as the reaction conditions and starting complexes. We have previously investigated the reactions of pyridine-2-thiol, 8 pyrimidine-2-thiol, 8 thiazole, 9,10 4-methylthiazole, 11 thiazolidine, 7 thiomorpholine, 7 benzothiazole, 6 and benzimidazole-2-thiol 6 with osmium and ruthenium carbonyl clusters and observed that the type of products obtained in these reactions are remarkably influenced by the intrinsic reactivity of the metal carbonyl clusters, the heterocyclic ligands and the reaction conditions.…”
Section: Introductionmentioning
confidence: 99%