1995
DOI: 10.1007/bf00241929
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Role of free F? anions in the electrorefining of titanium in molten alkali halide mixtures

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Cited by 22 publications
(14 citation statements)
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“…This observation was important because several papers have denied the suitability of all-chloride melts for the deposition of coherent titanium coatings (e.g. [18][19][20]). However, promising results from all-chloride melts have also been published by Haarberg et al and Duan et al [6,21].…”
Section: Morphologymentioning
confidence: 94%
“…This observation was important because several papers have denied the suitability of all-chloride melts for the deposition of coherent titanium coatings (e.g. [18][19][20]). However, promising results from all-chloride melts have also been published by Haarberg et al and Duan et al [6,21].…”
Section: Morphologymentioning
confidence: 94%
“…The ionic balance between Ti 2+ and Ti 3+ disappears when the value of [F]/[Ti] molar ratio across the red dot line (higher than 1.8). And then, the disproportionation reaction (6) dominates the concentration converting in the melt.…”
Section: Electrochemical Depositionmentioning
confidence: 99%
“…in fluoridechloride melt. 6) They present additional finding regarding its influence on the electrochemical parameters, E d and E p , the current efficiency, the morphology as well as the chemical purity of the electrodeposited titanium. The morphology of the cathodic deposit is mainly determined by the concentration of free fluoride anions in the melt.…”
Section: Introductionmentioning
confidence: 97%
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“…In order to verify the fitted results, the concentration of O 2¹ was disclosed by the yttria-stabilized zirconia electrode (YSZE). Moreover, it has been reported in some papers that the stability of the various oxidation states depends on the composition bath [10][11][12][13][14] which means different binary mixtures will show different equilibrium constant. Therefore, a series of experiments were carried out in molten binary mixtures of LiCl to clarify the influence of bath composition on the stability of the various oxidations.…”
Section: Introductionmentioning
confidence: 99%