The yearly waxing and waning of the seasonal polar caps represents one of the most dramatic expressions of the CO 2 cycle on Mars, with massive amounts of carbon dioxide cyclically exchanged between the atmosphere and the surface (Leighton & Murray, 1966). As CO 2 condenses on the surface (mainly in the local fall and winter), non-condensable species are left behind and accumulate in the atmospheric column, resulting in a decrease of the CO 2 partial pressure, and thus a reduction of the CO 2 frost point temperature 𝐴𝐴 𝐴𝐴CO 2 (Kieffer et al., 1976) from its 𝐴𝐴 𝐴𝐴 ⊖ CO 2 value for an atmospheric composition without CO 2 depletion by condensation. Throughout the robotic exploration of Mars, infrared brightness temperatures of the seasonal caps as low as ∼13 K below 𝐴𝐴 𝐴𝐴 ⊖ CO 2 have been observed, apparently in contradiction with expectations based on thermodynamic equilibrium of the CO 2 ice cap, which dictates 𝐴𝐴 𝐴𝐴 = 𝐴𝐴 ⊖ CO 2as long as gaseous CO 2 is available to condense (Leighton & Murray, 1966). These "cold spots" were attributed, at least in part, to enrichment