Attention to the most vulnerable road users has grown rapidly over recent decades. The experience gained reveals an important number of fatalities due to accidents in urban branch roads. In this study, an analytical methodology for the calculation of urban branch road safety is proposed. The proposal relies on data collected during road safety inspections; therefore, it can be implemented even when historical data about traffic volume or accidents are not available. It permits us to identify geometric, physical, functional, and transport-related defects, and elements which are causal factors of road accidents, in order to assess the risk of death or serious injuries for users. Traffic volume, average speed, and expected consequences on vulnerable road users in case of an accident allow us to calculate both the level of danger of each homogeneous section which composes the road, and the hazard index of the overall branch. A case study is presented to implement the proposed methodology. The strategy proposed by the authors could have a significant impact on the risk management of urban roads, and could be used in decision-making processes to design safer roads and improve the safety of existing roads.