2009
DOI: 10.1021/ja808888g
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Shape Discrimination with Hexapole−Dipole Interactions in Magic Angle Spinning Colloidal Magnetic Resonance

Abstract: We have studied the interactions between magnetically driven, DNA-linked anisotropic and isotropic colloidal rotors interacting via induced magnetic dipolar and multipolar forces. We show that a balance between magnetic dipole-dipole and dipole-hexapole interactions near the magic angle allows discrimination between spherical and anisotropic magnetic colloidal rotors.

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Cited by 11 publications
(10 citation statements)
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“…In this case the magnetic dipoledipole interactions have to be taken into account. Magic angle spinning may suppress the magnetic dipole or multipole interactions [25] such that the hydrodynamic interactions dominate.…”
Section: Conclusion and Discussionmentioning
confidence: 99%
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“…In this case the magnetic dipoledipole interactions have to be taken into account. Magic angle spinning may suppress the magnetic dipole or multipole interactions [25] such that the hydrodynamic interactions dominate.…”
Section: Conclusion and Discussionmentioning
confidence: 99%
“…They form dynamically induced self-organized structures depending on the particles' contours [7]. Magnetic dipolehexapol interactions may be used for separating rotors with respect to their shape [25]. Rotors also play an important role for bacterial motion such as the propulsion of Escherichia coli [3] with its rotating flagella.…”
Section: Introductionmentioning
confidence: 99%
“…Particles that have isotropic magnetizations, such as spherical paramagnetic particles (n = 1), interact solely with their dipoles. For ϑ = 0 • , time-averaged dipolar interactions are repulsive when Ψ is smaller than the magic angle 54.7º 20,21 , and attractive for Ψ > 54.7º. In contrast, chains (n > 1) additionally have higher-order magnetic moments due to spatially separated dipoles positioned at centers of particles that form the chains 20,22,23 .…”
Section: Pairwise Magnetic and Hydrodynamic Interactionsmentioning
confidence: 99%
“…For ϑ = 0 • , time-averaged dipolar interactions are repulsive when Ψ is smaller than the magic angle 54.7º 20,21 , and attractive for Ψ > 54.7º. In contrast, chains (n > 1) additionally have higher-order magnetic moments due to spatially separated dipoles positioned at centers of particles that form the chains 20,22,23 . For doublets (n = 2), the dominant repulsive multipolar interaction is the hexapole-dipole for Ψ < 61.5º, which decays rapidly with r -6 compared to the r -4 decay rate of the attractive dipolar interaction forces 20 .…”
Section: Pairwise Magnetic and Hydrodynamic Interactionsmentioning
confidence: 99%
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