Flexible
pressure sensors with high sensitivity and wide pressure
response range are attracting considerable research interest for their
potential applications as e-skins. Nowadays, it seems a dilemma to
realize high-performance, multifunctional pressure sensors with a
cost-effective, scalable strategy, which can simplify wearable sensing
systems without additional signal processing, enabling device miniaturization
and low power consumption. Herein, pressure sensors with ultrahigh
sensitivity and a broad response pressure range are developed with
a low-cost, facile method by combining strain-induced percolation
behavior and contact area contributions. Because of their special
surface structure and strain-induced conductive network formation
behavior, these unique pressure sensors exhibit wide sensing range
of 1 Pa to 500 kPa, ultrahigh sensitivity (1 × 106 and 3.1 × 104 kPa–1 in the pressure
ranges of 1 Pa to 20 kPa and 20–500 kPa, respectively), fast
signal response (<50 ms), low detection limit (1 Pa), and high
stability over 500 loading/unloading cycles. These characteristics
allow the devices to work as e-skins to monitor human pulse signals
and finger touch. Moreover, these sensors illustrate precise electrical
response to mechanical vibration, bending, and temperature stimuli,
which afford the ability of detecting cell phone call-in vibration
signals, joint bending, spatial pressure, and temperature distributions,
indicating promising applications in next-generation wearable, multifunctional
e-skins.