The article deals with technologies of refining and inoculating casting alloys with the use of nanostructured diamond powder, as well as stimulation technique on molten metal including processing of the liquid alloy with nanosecond electromagnetic pulses. The developed method of cast iron inoculation allows to eliminate the flare and to increase the physical and mechanical properties of the castings through the grain refining and the decrease of chilling tendency during crystallization of the liquid alloy. Inoculating of aluminium alloys by high-melting particles of a nanostructured diamond powder leads to the grinding of structural constituents, including conditions for dispersing hardening intermetallics during postbaking of such castings. As a result, foundry and physicomechanical properties of castings are significantly improved.