“…While after cross-linking, the EDS analysis shows a relative high oxygen content of 42.4%, indicating the introduction of massive oxygen. During the thermal cross-linking, the PCS will contact with air and amounts of oxygen can be introduced according to the following reaction [30,31]:…”
Section: Dielectric Properties Of Sic F /Sic-al 2 O 3 Composites At Hmentioning
“…While after cross-linking, the EDS analysis shows a relative high oxygen content of 42.4%, indicating the introduction of massive oxygen. During the thermal cross-linking, the PCS will contact with air and amounts of oxygen can be introduced according to the following reaction [30,31]:…”
Section: Dielectric Properties Of Sic F /Sic-al 2 O 3 Composites At Hmentioning
“…4. There were five vibrational bands at 3360 cm −1 , 2900 cm −1 , 2160 cm −1 , 976 and 885 cm −1 that were attributed according to the literature to ν N-H, ν C-H, ν Si-H, ν Si-N and δ Si-C bonds, respectively [21,24,25].…”
Section: Physicochemical Characterizations Of Si-zr-c-n Coatingsmentioning
“…In the absence of capillary forces (e.g., no liquid contact bridging), van der Waals forces become dominant for the adhesion between the pillars. Although the van der Waals forces are typically in the range of <100 nN, 32 the low stiffness of cross‐linked PCS (Young's modulus E of approximately 2.5 GPa) 7 facilitates micropillar bending. Bending of the free‐standing pillars of length l due to van der Waals adhesion force, F vdW , results in a deflection , which at a given point l z from the base is expressed by 31 where E is the elastic modulus and I is the moment of inertia.…”
Periodic patterns of silicon carbide (SiC) micropillars of 18 μm in length and 2 μm in diameter with a hexagonal morphology and an areal number density of micropillars of 6 × 104 mm−2 were fabricated from a mixture of two different polycarbosilane ceramic precursors. The polycarbosilanes (PCS) were molded into polydimethylsiloxane (PDMS) micromolds processed from a silicon wafer master. After cross‐linking between 200° and 400°C, debonding from the elastomeric PDMS mold yielded freestanding structures of PCS micropillars. Due to the low stiffness of cross‐linked PCS (E∼2.5 GPa), surface adhesion forces might result in the deformation of the micropillars into ordered domains. The PCS micropillar arrays were pyrolyzed in inert atmosphere at 900° and 1500°C to yield amorphous and nanocrystalline SiC (β‐SiC) with crystallite sizes in the range of tenths of micrometers, respectively. The formation of domains due to instability of micropillars with a high aspect ratio might be of specific interest for electrical engineering and catalytic applications.
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