In this paper, we present an electrical conductivity based rapid response and excellent recovery cigarette smoke sensor based on polyaniline/silicon carbide (Pani/SiC) nanocomposite prepared by in-situ chemical oxidative polymerization technique in an acidic medium. The Pani/SiC nanocomposites and polyaniline (Pani) were characterized by using Fourier transform infrared spectroscopy, x-ray diffraction, scanning electron microscopy and transmission electron microscopy. Results indicated that the well ordered nanocomposites were successfully prepared. The morphology and electrical properties of the nanocomposites were influenced by the extent of loading of SiC nanoparticles. The as-prepared materials were studied for the change in their electrical conductivity on exposure to cigarette smoke followed by ambient air at room temperature. It was observed that Pani/SiC-3 nanocomposite shows eight times higher amplitude of conductivity change than Pani on exposure cigarette smoke followed by ambient air. The conductivity response in the carbon monoxide, ammonia and methanol was also measured. It was observed that the carbon dioxide (CO 2 ) shows low response while in the case of methanol and ammonia the significant responses are observed, suggesting the possibility of contribution of above gases towards response against cigarette smoke. The cigarette smoke also contains many other volatile chemicals such as polyaromatic hydrocarbon (PAH), nicotine, hydrogen cyanide (HCN) and formaldehyde which may also interacted with polarons/bipolarons of polyaniline leading to decreasing in conductivity.