a b s t r a c tWe report on single-crystal rubrene field-effect transistors (FETs) with ferromagnetic Co electrodes, tunnel-coupled to the conduction channel via an Al 2 O 3 tunnel barrier. Magnetic and electronic characterization shows that the Al 2 O 3 film not only protects the Co from undesired oxidation, but also provides a highly controlled tunnel barrier for overcoming the conductivity mismatch problem when injecting spins from a ferromagnetic metal into a semiconductor. Our FETs provide a significant step towards the realization of a device that integrates FET and spin-valve functionality, one of the major goals of spintronics.Ó 2010 Elsevier B.V. All rights reserved.Both spin electronics (spintronics) and organic electronics have made their introduction in science and technology in the last few decades. Spintronics adds new functionality and economy to electronic devices by not only applying the electron's charge, but also its spin [1]. Organic materials particularly provide fabrication advantages, allowing for, e.g., light-weight and flexible electronics [2]. The merging of these two developments into the field of organic spintronics [3,4] not only potentially combines the advantages of both parental fields, but also provides additional value. Organic materials are expected to have long spin lifetimes, due to their low spin-orbit coupling and reduced hyperfine interaction, as compared to their inorganic counterparts [5]. This makes organic materials particularly interesting for application in spintronic devices.In this article, we have made a crucial step towards the application of organic single-crystals [6] for realizing spinvalve field-effect transistors (spin-valve FETs). The longrange order of these crystals makes them the organic semiconductors with the highest carrier mobility known at the moment [7]. They are therefore a logical choice for spinvalve FETs, in which both the scattering time and spin lifetime need to be sufficiently long [3]. Recent studies on organic single-crystal FETs have shown that a broad variety of materials can be used as source and drain electrodes with good performance. Since some of those materials are ferromagnetic [8][9][10], the question naturally arises whether the spin polarization of the electrodes can be used to inject spins into the accumulation layer of an organic FET, to realize an electrically controlled spin-valve, i.e. a spin-valve FET [11]. This is a highly desired -but, to the best of our knowledge, yet to be realized -goal in spintronics. Unfortunately, the ferromagnetic electrode materials used so far (nickel and cobalt) are not suitable without modifications, since their oxides are antiferromagnetic and would therefore cause spin randomization during the injection of charge carriers from the metal into the organic single-crystal. Moreover, the electrodes should be tunnelcoupled to the conduction channel in the organic single-1566-1199/$ -see front matter Ó