1998
DOI: 10.1002/(sici)1099-1581(1998100)9:10/11<593::aid-pat810>3.3.co;2-l
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Silicone derivatives as new flame retardants for aromatic thermoplastics used in electronic devices

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Cited by 98 publications
(36 citation statements)
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“…Recently, some specific branched methylphenylsiloxanes were found particularly effective in polycarbonate (PC) and in PC/acrylonitrilebutadrene-styrene (ABS) blends with a low (ABS) content. 79,80 It is believed that due to the inclusion of aromatic groups in the siloxane, it becomes significantly more soluble and more easily dispersed in PC than straight polydimethylsiloxane. It was shown that these siloxanes tend to migrate from the inside of the PC resin to the surface during combustion and accumulate quickly on the surface.…”
Section: Silicon Flame Retardantsmentioning
confidence: 99%
“…Recently, some specific branched methylphenylsiloxanes were found particularly effective in polycarbonate (PC) and in PC/acrylonitrilebutadrene-styrene (ABS) blends with a low (ABS) content. 79,80 It is believed that due to the inclusion of aromatic groups in the siloxane, it becomes significantly more soluble and more easily dispersed in PC than straight polydimethylsiloxane. It was shown that these siloxanes tend to migrate from the inside of the PC resin to the surface during combustion and accumulate quickly on the surface.…”
Section: Silicon Flame Retardantsmentioning
confidence: 99%
“…The presence of nitrogen compounds have had significant effect on flame resistance, as can be seen in the low flammability of wool, silk, and leather (Horacek and Grabner, 1996), triazines, isocyanates, urea, guanidine, and cyanuric acid derivatives are nitrogen-containing organic compounds and have been used as flame retardants (Horacek and Grabner, 1993). Silicon containing flame retardants have also been used (Iji, 1998;Zaikov and Lomakin, 1996). Boron-based compounds have also received extensive usage (Zing de, 1996).…”
Section: 1mentioning
confidence: 99%
“…They are endowed with excellent thermal stability and high heat resistance, with very limited release of toxic gases during thermal decomposition. Several types of silicone polymers were applied as flame retardants in polycarbonates (Iji & Serizawa, 1998). For the PC materials modified with branched methyl-and phenylsiloxanes and end-capped by methyl groups, limiting oxygen index (LOI) increased over 35 %, whereas LOI was about 27 % for pure PC.…”
Section: Silicones and Silica As Flame Retardant Additivesmentioning
confidence: 99%