Silver(i) coordination complexes and extended networks assembled from S, Se, Te substituted acenaphthenes

Control of Silver(I)–Dialkyl Chalcogenide Coordination by a Synthetic Cavity

“…The integral ratio of selenide 2 a to cage 1 remained unchanged, and these combined results strongly suggested the formation of ternary complex 1 ⋅[Ag I ⋅( 2 a ) 2 ]. Selenide coordination was also supported by the upfield‐shifted signal in the 77 Se NMR spectrum (Figure 1 g),5f–h and the disappearance of the CT absorption band (Supporting Information, Figure S8). When an additional selenide ligand 2 a was introduced into the solution of 1 ⋅[Ag I ⋅( 2 a ) 2 ], the number of ligand 2 a coordinated to the silver center did not increase.…”

A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure

“…16,17 Furthermore, the silver(I) complexes have found different applications in material science for their structural diversity originating from a d 10 electron configuration which allows the formation of different coordination geometries and represent a foundation for construction of supramolecular frameworks. 18,19,20 Herein we report the crystal structure of first silver coordination compound with bdmpza ligands. The compound was also characterized by Hirshfeld surface analysis, coupled thermogravimetric-mass spectrometry analysis and infrared spectroscopy.…”

Diverse silver(i) sulfobenzoate coordination polymers and their recycling property as homogeneous catalyst in oxygenation of sulfide

“…[3][4][5][6][7] Coordination polymers developed from silver ions and heterocyclic nitrogen ligands continue to attract attention due to the coordinative sites of the d 10 silver(I) ion varying from 2 to 6 and its various geometries (linear, trigonal, tetrahedral, trigonal, pyramidal, and octahedral). [8][9][10][11] The supramolecular chemistry of Ag(I) coordination polymers represents a dynamic and thriving eld which abounds with various supramolecular forces such as metal-ligand, metal-p, and metal-metal interactions, hydrogen bonds, p-p stacking, and anion interactions. 10,[12][13][14] Therefore the crystallization of Ag(I) complexes would depend on the delicate balance of thermodynamic and kinetic contributions concerning synergetic supramolecular interactions, which may account for the fact that the structures and topologies of Ag(I) complexes can be astonishingly varied even if they have similar ligands.…”

“…[8][9][10][11] The supramolecular chemistry of Ag(I) coordination polymers represents a dynamic and thriving eld which abounds with various supramolecular forces such as metal-ligand, metal-p, and metal-metal interactions, hydrogen bonds, p-p stacking, and anion interactions. 10,[12][13][14] Therefore the crystallization of Ag(I) complexes would depend on the delicate balance of thermodynamic and kinetic contributions concerning synergetic supramolecular interactions, which may account for the fact that the structures and topologies of Ag(I) complexes can be astonishingly varied even if they have similar ligands. 12,15,16 Sulfobenzoates with sulfonate and carboxylate groups are useful synthetic synthons which can develop multimodal and polydentate coordinative systems.…”