Simultaneous determination of pesticides and their degradation products in potatoes by MSPD-LC-MS/MS

Danek, Magdalena; Fang, Xun; Ji, Tang; Płonka, Joanna; Barchańska, Hanna

doi:10.1016/j.jfca.2021.104129

Cited by 16 publications

(3 citation statements)

References 23 publications

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“…Česnik et al (2006) detected pesticide residues above EU-MRL in 23% of 150 potato samples from Slovene. Danek et al (2021) detected residues above EU-MRL in 8 of 15 potato samples from markets in Poland. Česnik et al (2010) detected residues below LOQ in all 52 potato samples from Slovene.…”

Section: Residue Analyses In Potatoesmentioning

confidence: 99%

LC-MS/MS ve GC-MS ile Türkiye menşeli patateslerde insektisit kalıntılarının araştırılması ve sağlık risk değerlendirmesi

Yılmaz

Balkan²

2023

TED

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Insecticide, acaricide, nematicide and metabolite residues were assayed in 104 potato samples collected from local markets in Tokat, Türkiye in 2022 and the potential health risk for consumers assessed. Analytical method verification was performed for 135 pesticide active substances in potato matrices by liquid chromatography-tandem mass spectrometry and gas chromatography-mass spectrometry. Matrix-matched calibration curves were constructed and good linearity was obtained with a coefficient of determination between 0.990 and 0.999. Average recoveries varied from 73.2 to 119.6%. Repeatability and intra-laboratory reproducibility conditions of the method expressed as %RSD were less than 20%. These figures were within the SANTE/11312/2021 recovery limits (70-120%) and the values specified for the repeatability (RSD ≤ 20%). The limits of quantification were lower than the maximum residue limits set by the European Union for the potato. No pesticide residues were found at detectable limits in 93 samples. Two samples contained residues below the maximum residue limit (MRL), while nine samples contained residues above the MRLs. Clothianidin and thiamethoxam residues detected in one sample, while acetamiprid were detected in nine samples. The health risk assessment study indicated that potato consumption was safe for consumers.

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Section: Residue Analyses In Potatoesmentioning

confidence: 99%

LC-MS/MS ve GC-MS ile Türkiye menşeli patateslerde insektisit kalıntılarının araştırılması ve sağlık risk değerlendirmesi

Yılmaz

Balkan²

2023

TED

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“…The multiple-reaction-monitoring (MRM) conditions were optimized with infusion of derivatized thiols at 10 μL/min. Based on the mass spectra ( Supplementary Figure 1 ) with the MassLynx software using the sample tune and develop method, two ion transitions were chosen for the quantification (quantifier) and the confirmation (qualifier) ( 23 ). Table 1 lists the best MRM parameters for each derived thiol with the following instrument settings: capillary voltage, 3 kV; desolvation temperature, 500°C; gas, 800 L/h.…”

Section: Methodsmentioning

confidence: 99%

Characterization of volatile thiols in Chinese liquor (Baijiu) by ultraperformance liquid chromatography–mass spectrometry and ultraperformance liquid chromatography–quadrupole-time-of-flight mass spectrometry

Yan

Lu²,

Nie³

et al. 2022

Front. Nutr.

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Volatile thiols give a unique flavor to foods and they have been extensively studied due to their effects on sensory properties. The analytical assay of volatile thiols in food is hindered by the complexity of the matrix, and by both their high reactivity and their typically low concentrations. A new ultraperformance liquid chromatography (UPLC) strategy has been developed for the identification and quantification of volatile thiols in Chinese liquor (Baijiu). 4,4’-Dithiodipyridine reacted rapidly with eight known thiols to form derivatives, which provided a diagnostic fragment ion (m/z 143.5) for tandem mass spectrometry (MS/MS). To screen for new thiols, Baijiu samples were analyzed by means of UPLC–MS/MS screening for compounds exhibiting the diagnostic fragment ion (m/z X→143.5). New peaks with precursor ions of m/z 244, 200 and 214 were detected. Using UPLC with quadrupole-time-of-flight mass spectrometry (UPLC–Q-TOF–MS) and authentic standards, ethyl 2-mercaptoacetate, 1-butanethiol, and 1-pentanethiol were identified in Baijiu for the first time. Commercial Baijiu samples were analyzed with the new method and the distribution of 11 thiols was revealed in different Baijiu aroma-types. The aroma contribution of these thiols was evaluated by their odoractivity values (OAVs), with the result that 7 of 11 volatile thiols had OAVs > 1. In particular, methanethiol, 2-furfurylthiol, and 2-methyl-3-furanthiol had relatively high OAVs, indicating that they contribute significantly to the aroma profile of Baijiu.

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“…These detectors include the flame photometric detector, electron capture detector, and nitrogen phosphorus detector . The most popular methods, however, are gas chromatography–tandem mass spectrometry, , gas chromatography–mass spectrometry, , and liquid chromatography–tandem mass spectrometry. − LC–MS/MS is currently the technology of choice for determining pesticide residues . This is on account of the fact that LC–MS/MS is significantly superior to GC–MS/MS regarding sensitivity, range, and selectivity, coupled with the capability to process most determinations without derivatization.…”

Section: Introductionmentioning

confidence: 99%

Simultaneous Determination of 26 Pesticide Residues in Traditional Chinese Medicinal Leeches by Modified QuEChERS Coupled with HPLC–MS/MS

Zhou

Huang

et al. 2023

ACS Omega

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A Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) pretreatment technique combined with HPLC–MS/MS was established to detect 26 pesticides in traditional Chinese medicinal leeches. The sample was extracted by acetonitrile solution with sodium acetate-0.1% (v/v) acetic acid as a buffer system, then cleaned up by a mixture of 750 mg of MgSO4, 150 mg of C18, and 150 mg of PSA, separated by an ACQUITY BEH C18 column, and determined in the dynamic multiple reaction mode. Under the optimized conditions, the peak areas of the 26 pesticides in leeches showed good linearity (r > 0.99) between their mass concentrations from 1 to 100 μg/L. At the spike levels of 10, 20, and 100 μg/kg, the recoveries of 26 pesticides in leeches were 72.9–101.6% with an RSD of 1.1–12.8%, an LOQ of 10 μg/kg, and an LOD of 0.1–5.4 μg/kg. This method is easy, rapid, sensitive, and practical and meets the requirements of pesticide residue detection standards.

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Simultaneous determination of pesticides and their degradation products in potatoes by MSPD-LC-MS/MS

Cited by 16 publications

References 23 publications

LC-MS/MS ve GC-MS ile Türkiye menşeli patateslerde insektisit kalıntılarının araştırılması ve sağlık risk değerlendirmesi

LC-MS/MS ve GC-MS ile Türkiye menşeli patateslerde insektisit kalıntılarının araştırılması ve sağlık risk değerlendirmesi

Characterization of volatile thiols in Chinese liquor (Baijiu) by ultraperformance liquid chromatography–mass spectrometry and ultraperformance liquid chromatography–quadrupole-time-of-flight mass spectrometry

Simultaneous Determination of 26 Pesticide Residues in Traditional Chinese Medicinal Leeches by Modified QuEChERS Coupled with HPLC–MS/MS

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