The research work carried out in this doctoral thesis has focused on the study of High Capacity Optical Networks. This work contributes to the development of new methodologies and techniques, mainly based on the polarization management of the optical signal. The objective, and main motivation of this work is to give a solution to the imposed limitations by some factors, such as polarization mode dispersion (PMD) or non-linear effects in the optical fiber.It is important to highlight that the scope of the proposals developed in this thesis include both the legacy DWDM (Dense Wavelength Division Multiplexing) networks, coming from the beginning of the 2000s that are currently working and the new generation Optical Networks.The obtained results have been fundamentally based on the design and characterization of simulated optical systems by a commercial program. However, a part of the contributions of this thesis have been validated by experimental characterization of different optical links.In the legacy networks, the most important limiting factor is the PMD, due to the worn-out of fiber optic cables. This parameter is very dependent on environmental elements, especially in aerial lines. In order to improve understanding of how PMD behaves in different environmental situations, long-term PMD measurements have been performed using an interferometric method. This has allowed to characterizing their random behavior and determining the effects that external agents such as temperature, humidity and wind speed have on the PMD.The experimental results have been compared with the PMD prediction model, this comparison allow us to validate the interferometric method as the best option for long-term and broad-spectrum measurements.In addition, we propose a new approach model for the catenary. This model is able to estimate the fiber birefringence caused by the torsion and flexion of an aerial cable due to high wind speed conditions.Regarding the legacy networks in which the modulation format usually used is RZ-DQPSK (Return to Zero -Differential Quadrature Phase-Shift Keying), this work proposes the compensation of the nonlinear effects, such as the FWM (Four-wave mixing) and more especially the intrachannel IFWM, by depolarizing the optical signal using fibers with a certain PMD value.On the other hand, a commercial DWDM legacy optical route has also been analyzed, characterized and measured in order to improve its performance, considering as much as possible the economic implications derived from the migration to higher technologies. An analytical study of limiting factors of the route has been carried out, which has included the tolerance to the concatenation of filters, to the amplified spontaneous emission (ASE) introduced by the optical in-line amplifiers (OLA), and compared with the experimental measurements.Based on the results obtained, the possibility of increasing the capacity of a legacy DWDM network has been demonstrated. It has been proposed, among other things, the use of coherent receivers to improve the OSNR ...