We have investigated the electrocaloric properties of K + and Na + co-substituted Sr 0.6 Ba 0.4 Nb 2 O 6 (SBN) ceramics using the indirect method. Tetragonal tungsten bronze (K 0.5 Na 0.5 ) 2x (Sr 0.6 Ba 0.4 ) 5-x Nb 10 O 30 (KNSBN) with x = 0.24 was synthesized using dual-step sintering. Despite the low amount, K + and Na + co-substitution resulted in normal ferroelectric behaviour, showing no significant shift in the dielectric maximum temperature of 111°C with increasing frequency. Maximum electrocaloric temperature change (ΔT) of 0.3 K was observed at an electric field of 30 kV/cm (ΔE) yielding the largest electrocaloric responsivity (ΔT/ΔE) among SBN based ceramics. This relatively large value is in agreement with the larger pyroelectric coefficient of KNSBN compared to SBN based ceramics.