“…During the past few years, vanadium oxides based materials have attracted much attention due to their fascinating structures and electronic, optical, and magnetic properties, which are relevant to such diverse areas as lubrication, chemical sensor, catalysis, cathode materials in batteries, and minerals [1][2][3][4][5][6]. Stimulated by those applications, much work has been done on the synthesis and characterization of various vanadium compounds such as LiV 3 O 8 [7], CuV 2 O 6 [8], and nickel(II) hybrid vanadates [9]. Zn 3 (VO 4 ) 2 has an interesting crystal structure that is of porous framework.…”