Solid-supported palladium nano and microparticles: an efficient heterogeneous catalyst for ligand-free Suzuki–Miyaura cross coupling reaction

BiCl3‐catalyzed carbon‒carbon cross‐coupling of organoboronic acids with aryl iodides

“…[7][8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23] Over the last three decades, the Suzuki coupling reaction has become unarguably the most efficient method for the C-C bond formation. In this regard, transition and nontransition metals such as copper, [25][26][27] cobalt, [28] iron, [29][30][31][32][33][34] nickel, [34][35][36][37][38] zinc, [39] indium, [40] solid supported catalyst [41][42][43][44] and nano particles [45][46][47][48][49] have been used for C-C cross-coupling reactions. [24] In subsequent developments, various inexpensive and environmentally benign catalysts have been developed for C-C cross-coupling reactions.…”

Chemically modified polysulfone membrane containing palladium nanoparticles: Preparation, characterization and application as an efficient catalytic membrane for Suzuki reaction

“…For this instance, as standard reaction, reaction of idobenzene and phenyl boronic acid was selected and catalytic reaction was performed. The reaction were proceeded smoothly to offer biphenyl in water (solvent) and compared to the literature (Das et al, 2011;He and Cai, 2011;Liu et al, 2010) can say that catalytic membranes showed good catalytic activity in short time (Table 1). The reusability of a catalytic membrane is one of the most important factor which determines its profitability for commercial applications.…”

Eco-Friendly Physical Activation Methods for Suzuki–Miyaura Reactions

“…[136] An US-induced continuous flow technique has been developed by Shil et al [137] for the gram scale SMC reaction of haloarenes (chloro, bromo and iodo) with phenylboronic acid catalyzed by solid supported Pd(0) nano/microparticle (SS-Pd). They previously reported [138] a facile process for the in situ generation of Pd(0) nano-and microparticles and their stable deposition over the amberlite IRA 900 resin. The hydrophobic and hydrophilic combination of the borohydride exchanged polymer used for SS-Pd preparation played a crucial role in reducing the Pd(II) ion to Pd(0), and impregnating it into the hydrophobic pockets of the polymer matrix as nano-and microparticles.…”