“…Modern instrumental approaches to determine trace metals and asphaltenes in crude oil is by means of physical methods. Analytical methods were developed for the determination of metals in crude oils and derivatives using various analytical techniques, including flame atomic absorption spectrometry (FAAS) [55], graphite furnace atomic absorption spectrometry (GFAAS) [56], inductively coupled plasma optical-emission spectroscopy (ICP-OES) [57], inductively coupled plasma-mass spectrometry (ICP-MS) [58], X-ray fluorescence spectroscopy [59], spectrophotometry [60], and high-performance liquid chromatography (HPLC) [61]. To date, concentrations of these metals in petroleum have mostly been determined by ICP-OES and ICP-MS because of their distinguished sensitivity, repeatability, and operability [62].…”