Hydrophobic–hydrophilic
hybrid surfaces, sometimes termed
biphilic surfaces, have shown potential to enhance condensation and
boiling heat transfer, anti-icing, and fog harvesting performance.
However, state of art techniques to develop these surfaces have limited
substrate selection, poor scalability, and lengthy and costly fabrication
methods. Here, we develop a simple, scalable, and rapid stamping technique
for hybrid surfaces with spatially controlled wettability. To enable
stamping, rationally designed and prefabricated polydimethylsiloxane
(PDMS) stamps, which are reusable and independent of the substrate
and functional coating, were used. To demonstrate the stamping technique,
we used silicon wafer, copper, and aluminum substrates functionalized
with a variety of hydrophobic chemistries including heptadecafluorodecyltrimethoxy-silane,
octafluorocyclobutane, and slippery omniphobic covalently attached
liquids. Condensation experiments and microgoniometric characterization
demonstrated that the stamped surfaces have global hydrophobicity
or superhydrophobicity with localized hydrophilicity (spots) enabled
by local removal of the functional coating during stamping. Stamped
surfaces with superhydrophobic backgrounds and hydrophilic spots demonstrated
stable coalescence induced droplet jumping. Compared to conventional
techniques, our stamping method has comparable prototyping cost with
reduced manufacturing time scale and cost. Our work not only presents
design guidelines for the development of scalable hybrid surfaces
for the study of phase change phenomena, it develops a scalable and
rapid stamping protocol for the cost-effective manufacture of next-generation
hybrid wettability surfaces.