Si layers were developed on pre-oxidized Si wafers by decomposition of silane in a low pressure chemical vapour deposition reactor. By keeping the deposition time constant (2 min) three sets of samples were fabricated at deposition temperatures equal to 580, 610 and 625 • C. The deposited Si layers were thinned by high temperature dry oxidation thus forming SiO 2 /Si/SiO 2 structures. Room temperature photoluminescence (PL) measurements showed that for those samples in which the thickness of the remaining Si layer was greater than ∼6 nm, the spectra exhibited a peak at ∼650 nm. Prolonged oxidations led to the formation of SiO 2 /nanocrystalline-Si/SiO 2 structures in which the thickness of the remaining nanocrystalline Si (nc-Si) layer was smaller than 3 nm. The PL spectra obtained from these structures were at least ten times stronger compared to the previous ones. The PL peak wavelength exhibited a weak dependence on the nc-Si layer thickness shifting from 800 to 720 nm for nc-Si thickness decreasing from ∼3 to ∼0.5 nm. In this publication we present our experimental findings, which indicate that the intensity of the 720-800 nm PL band is influenced by the deposition temperature of the initial Si layer and by the thickness of the oxide layer between the nc-Si layer and the Si substrate.