2012
DOI: 10.1002/adma.201202749
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Stacking‐Order‐Dependent Optoelectronic Properties of Bilayer Nanofilm Photodetectors Made From Hollow ZnS and ZnO Microspheres

Abstract: Innovative bilayer nanofilms composed of semiconducting ZnS and ZnO hollow microspheres are successfully fabricated by an oil-water interfacial self-assembly strategy. The photocurrent of the bilayer film-based photodetectors is dependent on the stacking orders of the building blocks. The optimal optoelectronic properties of the ZnS(up)/ZnO(down) device are much better than those of the monolayer-film based device.

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Cited by 137 publications
(132 citation statements)
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References 31 publications
(18 reference statements)
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“…Also due to barrier height of NiO, it helps to block the photogenerated carriers to flow back and hence M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT 12 prevents the recombination of e-h pairs [14]. The photoresponsivity (R) of the fabricated photodiodes is defined as the ratio of photocurrent to that of input power of the UV light source and calculated using the following relation [15,38,40] x 10 2 % and 1.87 x 10 3 % respectively. The detectivity (D) of the fabricated photodiodes is calculated using the following relation [15,40] M A N U S C R I P T…”
Section: Fabrication and Characterization Of Uv-photodiodesmentioning
confidence: 99%
“…Also due to barrier height of NiO, it helps to block the photogenerated carriers to flow back and hence M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT 12 prevents the recombination of e-h pairs [14]. The photoresponsivity (R) of the fabricated photodiodes is defined as the ratio of photocurrent to that of input power of the UV light source and calculated using the following relation [15,38,40] x 10 2 % and 1.87 x 10 3 % respectively. The detectivity (D) of the fabricated photodiodes is calculated using the following relation [15,40] M A N U S C R I P T…”
Section: Fabrication and Characterization Of Uv-photodiodesmentioning
confidence: 99%
“…Moreover, in the structures of nanoshells, a well-ordered bilayer nanofilm utilizing wurtzite ZnS (≈3.7 eV, 340 nm) and ZnO (≈3.4 eV, 370 nm) hollow microspheres is also developed as active materials for the photodetectors. 46 Their photoresponsive properties are found to depend dominantly on the stacking orders of the hollow microspheres in the multilayer films. As shown in Figure 3h, when the ZnS shells are stacked on the top of ZnO shells, the WGM resonances are strong, owing to the lower refractive index of ZnO as compared to the one of ZnS.…”
Section: −52mentioning
confidence: 99%
“…Figure 3j illustrates the on/off switching of the bilayer device under UV irradiation at a bias of 5 V. All of the device time responses are highly stable and reproducible, and especially no degradation is observed in tens of switching cycles, indicating the excellent stability and fast response speed of the devices. 46 Light Management for PV Devices. Conventional Strategies for PV Device Light Management.…”
Section: −52mentioning
confidence: 99%
“…TiO 2 hollow sphere doping 9.4 mol% Ag has excellent antibacterial activities against scherichia coli, staphylococcus aurels and candida albicans at room temperature. Furthermore, hollow spheres with photocatalytic properties can be photoelectric detector [96].…”
Section: Other Applicationmentioning
confidence: 99%