Structural and Optical Studies of Cadmium Sulfide Quantum Dot-Graphene Oxide-Chitosan Nanocomposite Thin Film as a Novel SPR Spectroscopy Active Layer

Saleviter, Silvan; Fen, Yap Wing; Omar, Nur Alia Sheh; Daniyal, ‬Wan Mohd Ebtisyam Mustaqim Mohd; Abdullah, Jaafar; Zaid, Mohd Hazani Mat

doi:10.1155/2018/4324072

Cited by 27 publications

(12 citation statements)

References 39 publications

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“…For the sensing part, it was stated that the CdS QDs-GO-Cs changed the refractive index of the active layer, resulting in a shift in the resonance angle. [137]…”

Section: Emergence Of Surface Plasmon Resonance As Alternative Optmentioning

confidence: 99%

Development of Graphene Quantum Dots-Based Optical Sensor for Toxic Metal Ion Detection

Anas

Fen

Omar

et al. 2019

Sensors

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About 71% of the Earth’s surface is covered with water. Human beings, animals, and plants need water in order to survive. Therefore, it is one of the most important substances that exist on Earth. However, most of the water resources nowadays are insufficiently clean, since they are contaminated with toxic metal ions due to the improper disposal of pollutants into water through industrial and agricultural activities. These toxic metal ions need to be detected as fast as possible so that the situation will not become more critical and cause more harm in the future. Since then, numerous sensing methods have been proposed, including chemical and optical sensors that aim to detect these toxic metal ions. All of the researchers compete with each other to build sensors with the lowest limit of detection and high sensitivity and selectivity. Graphene quantum dots (GQDs) have emerged as a highly potential sensing material to incorporate with the developed sensors due to the advantages of GQDs. Several recent studies showed that GQDs, functionalized GQDs, and their composites were able to enhance the optical detection of metal ions. The aim of this paper is to review the existing, latest, and updated studies on optical sensing applications of GQDs-based materials toward toxic metal ions and future developments of an excellent GQDs-based SPR sensor as an alternative toxic metal ion sensor.

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“…For the sensing part, it was stated that the CdS QDs-GO-Cs changed the refractive index of the active layer, resulting in a shift in the resonance angle. [137]…”

Section: Emergence Of Surface Plasmon Resonance As Alternative Optmentioning

confidence: 99%

Development of Graphene Quantum Dots-Based Optical Sensor for Toxic Metal Ion Detection

Anas

Fen

Omar

et al. 2019

Sensors

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“…Surface plasmon resonance (SPR) sensing. SPR measurements were conducted based on Kretschmann configuration [65][66][67][68] by evaporating Au/DSU/NH 2 rGO-PAMAM/IgM sensor film onto the prism surface. The prism was placed on an optical stage driven by a stepper motor with a resolution of 0.001° (Newport MM 3000) to let the incident light from laser beam (632.8 nm, 5 mW) pass through the prism and hits a gold layer to generate the surface plasmon waves at the interface.…”

mentioning

confidence: 99%

Sensitive Detection of Dengue Virus Type 2 E-Proteins Signals Using Self-Assembled Monolayers/Reduced Graphene Oxide-PAMAM Dendrimer Thin Film-SPR Optical Sensor

Omar

Fen

Abdullah

et al. 2020

Sci Rep

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In this work, sensitive detection of dengue virus type 2 E-proteins (DENV-2 E-proteins) was performed in the range of 0.08 pM to 0.5 pM. The successful DENV detection at very low concentration is a matter of concern for targeting the early detection after the onset of dengue symptoms. Here, we developed a SPR sensor based on self-assembled monolayer/reduced graphene oxide-polyamidoamine dendrimer (SAM/NH 2 rGO/PAMAM) thin film to detect DENV-2 E-proteins. Surface characterizations involving X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR) confirms the incorporation of NH 2 rGO-PAMAM nanoparticles in the prepared sensor films. The specificity, sensitivity, binding affinity, and selectivity of the SPR sensor were then evaluated. Results indicated that the variation of the sensing layer due to different spin speed, time incubation, and concentration provided a better interaction between the analyte and sensing layer. The linear dependence of the SPR sensor showed good linearity (R 2 = 0.92) with the lowest detection of 0.08 pM DENV-2 E-proteins. By using the Langmuir model, the equilibrium association constant was obtained at very high value of 6.6844 TM −1 (R 2 = 0.99). High selectivity of the SPR sensor towards DENV-2 E-proteins was achieved in the presence of other competitors. Dengue virus (DENV) is the most common arthropod-borne viral disease that poses a serious global problem. According to World Health Organization (WHO), the dengue virus is the leading cause of death of 22 000, annually. As of today, the need for hospitalization and medical treatment are constantly dense due to the fact that 390 million people in the world are still infected with DENV 1. Its four distinct serotypes (DENV-1. DENV-2, DENV-3, and DENV-4) are capable of causing a range of clinical symptoms ranging from mild fevers to the severe dengue haemorrhagic fever (DHF) and be potentially life-threatening 2-10. Despite its large burden to human health, no effective vaccine and antiviral therapy are available for the virus 11,12. Early treatment for DENV is only by maintaining the body fluid of the patient, as it is critical in fighting the severe symptoms of DENV 13,14. Hence, an early, rapid, and accurate diagnosis at the onset of infection is the demand of the day in the most epidemic settings. Present discoveries in dengue diagnostics that can help in the early diagnosis are targeting the host-virus itself. DENV consists of a single-stranded positive-sense RNA virus that encodes 10 different types of proteins. Seven of

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“…Sulfide quantum dots commonly included central sulfide nanodots, especially metal sulfide, and surface functional groups. Much research efforts have been devoted to synthesize sulfide quantum dots, such as ZnS, CdS, PbS, Ag 2 S, SnS 2 , In 2 S 3 and AgInZnS quantum dots [ 87 , 88 , 89 , 90 , 91 , 92 ].…”

Section: Sulfur-containing Quantum Dotsmentioning

confidence: 99%

Biosensors Based on Advanced Sulfur-Containing Nanomaterials

Wang

Jiang

et al. 2020

Sensors

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In recent years, sulfur-containing nanomaterials and their derivatives/composites have attracted much attention because of their important role in the field of biosensor, biolabeling, drug delivery and diagnostic imaging technology, which inspires us to compile this review. To focus on the relationships between advanced biomaterials and biosensors, this review describes the applications of various types of sulfur-containing nanomaterials in biosensors. We bring two types of sulfur-containing nanomaterials including metallic sulfide nanomaterials and sulfur-containing quantum dots, to discuss and summarize the possibility and application as biosensors based on the sulfur-containing nanomaterials. Finally, future perspective and challenges of biosensors based on sulfur-containing nanomaterials are briefly rendered.

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Structural and Optical Studies of Cadmium Sulfide Quantum Dot-Graphene Oxide-Chitosan Nanocomposite Thin Film as a Novel SPR Spectroscopy Active Layer

Cited by 27 publications

References 39 publications

Development of Graphene Quantum Dots-Based Optical Sensor for Toxic Metal Ion Detection

Development of Graphene Quantum Dots-Based Optical Sensor for Toxic Metal Ion Detection

Sensitive Detection of Dengue Virus Type 2 E-Proteins Signals Using Self-Assembled Monolayers/Reduced Graphene Oxide-PAMAM Dendrimer Thin Film-SPR Optical Sensor

Biosensors Based on Advanced Sulfur-Containing Nanomaterials

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