A fluorite-related phase of Gd 2 O 3 , with a tetragonal unit cell of aϭ5.65 Å and cϭ5.37 Å, was attained in this study. The new phase was found either in a thin Gd 2 O 3 film ͑ϳ18 Å͒, which was epitaxially grown on GaAs͑100͒, or in a disordered ͑by mild Ne ϩ -ion sputtering͒ and recrystallized ͑by UHV annealing͒ thin cubic ␣-Gd 2 O 3 film. The structural characteristics of the new oxide films were studied using in situ reflection high-energy electron diffraction, secondary-electron imaging, and single-crystal x-ray diffraction.