Identification of the prevailing radiation defects of large density remains a considerable issue for particle detectors made of high resistivity Si. To clarify the dominant radiation induced traps within CERN standard Si pad detectors, the capacitance (C-) and current (I-) deep level transient spectroscopy (DLTS) techniques have been combined. Additionally, the optical (O-) injection I-DLTS regime has been employed to cover a wide range of neutron irradiation fluences of 10 12-10 16 cm-2. The spectra of C-DLTS and O-I-DLTS have been recorded using the temperature scans in the range of 20-300 K. The radiation induced vacancy (V) attributed defects such as V-O, V 2 , and clusters have been identified, the density of which increases with irradiation fluence in the range of 10 12-10 14 cm-2 , while this density saturates for the collected neutron fluence of more than 10 14 cm-2 .