1973

DOI: 10.1016/s0040-4020(01)93288-0

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Substituent effect on the IR and PMR spectra of diphenylamines

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Cited by 20 publications

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Hydrogen Bonds of Anilines

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2009

Patai's Chemistry of Functional Groups

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Introduction Self‐Association of Anilines Intramolecular Hydrogen Bonds Intermolecular Hydrogen Bonds Hydrogen Bonds in Polyanilines Halogen Bonds in Anilines

Hydrogen Bonds of Anilines

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2009

Patai's Chemistry of Functional Groups

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Introduction Self‐Association of Anilines Intramolecular Hydrogen Bonds Intermolecular Hydrogen Bonds Hydrogen Bonds in Polyanilines Halogen Bonds in Anilines

Untersuchungen zum Mechanismus der thermischen Umlagerung von Tetraarylhydrazinen. Die Thermolyse einiger deuterierter Tetraarylhydrazine

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1975

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Die Thermolyse der deuterierten Tetraphenylhydrazine 9 und 20-22 zeigt, daD die Umlagerung zu den Semidinen wie 4 und 5 intermolekular verlauft, und daO die Radikaldimeren-Zwischenstufen vom Typ 2 und 3 rascher zu den Semidinen tautomerisieren als in Diarylaminyle zuriickspalten. A Mechanistic Study of the Thermal Rearrangement of Tetraarylhydrazines. The Thermolysis of Some Deuterated TetraarylhydraziaesIn the thermolysis of the deuterated tetraphenylhydrazines 9 and 20 -22it was found that rearrangement to the semidines (e. g. 4 and 5) proceeds intermolecularly. Tautomerization of the radical dimer intermediates (as 2 and 3) to semidines is faster than their dissociation into diarylaminyls.Tetraphenylhydrazin (1) liefert beim Erhitzen in einem organischen Losungsmittel ein komplexes Gemisch von Reaktionsprodukten, das mit den Semidinen 4 und 5 zwei Isomere von 1 enthalt 1*2). Semidin-Bildung ist auch h i der Thermolyse anderer Tetraarylhydrazine beobachtet worden '). Als erster Schritt dieser Umlagerung wird die Spaltung der Hydrazine zu Diarylstickstoff-Radikalen angesehen [s. Schema (l)

ChemInform Abstract: SUBSTITUENTENEFFEKTE AUF IR‐ UND (1)H‐NMR‐SPEKTREN VON M‐ UND P‐SUBSTITUIERTEN DIPHENYLAMINEN

et al. 1973

Chemischer Informationsdienst

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